Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters

Symmetry breaking and amplification processes play a fundamental role in nature and technology. Here, the authors show that the interplay between racemization and ligand exchange leads to amplification of enantiomeric excess of intrinsically chiral metal clusters.

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Autores principales:	Yanan Wang, Belén Nieto-Ortega, Thomas Bürgi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/912f1b6a348d44e9b5cdb353e96d0eef
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spelling	oai:doaj.org-article:912f1b6a348d44e9b5cdb353e96d0eef2021-12-02T17:42:05ZAmplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters10.1038/s41467-020-18357-02041-1723https://doaj.org/article/912f1b6a348d44e9b5cdb353e96d0eef2020-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-18357-0https://doaj.org/toc/2041-1723Symmetry breaking and amplification processes play a fundamental role in nature and technology. Here, the authors show that the interplay between racemization and ligand exchange leads to amplification of enantiomeric excess of intrinsically chiral metal clusters.Yanan WangBelén Nieto-OrtegaThomas BürgiNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yanan Wang Belén Nieto-Ortega Thomas Bürgi Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters
description	Symmetry breaking and amplification processes play a fundamental role in nature and technology. Here, the authors show that the interplay between racemization and ligand exchange leads to amplification of enantiomeric excess of intrinsically chiral metal clusters.
format	article
author	Yanan Wang Belén Nieto-Ortega Thomas Bürgi
author_facet	Yanan Wang Belén Nieto-Ortega Thomas Bürgi
author_sort	Yanan Wang
title	Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters
title_short	Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters
title_full	Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters
title_fullStr	Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters
title_full_unstemmed	Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters
title_sort	amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of au38 clusters
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/912f1b6a348d44e9b5cdb353e96d0eef
work_keys_str_mv	AT yananwang amplificationofenantiomericexcessbydynamicinversionofenantiomersinderacemizationofau38clusters AT belennietoortega amplificationofenantiomericexcessbydynamicinversionofenantiomersinderacemizationofau38clusters AT thomasburgi amplificationofenantiomericexcessbydynamicinversionofenantiomersinderacemizationofau38clusters
_version_	1718379657867296768

Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters

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