Amplification of enantiomeric excess by dynamic inversion of enantiomers in deracemization of Au38 clusters

Symmetry breaking and amplification processes play a fundamental role in nature and technology. Here, the authors show that the interplay between racemization and ligand exchange leads to amplification of enantiomeric excess of intrinsically chiral metal clusters.

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Bibliographic Details
Main Authors: Yanan Wang, Belén Nieto-Ortega, Thomas Bürgi
Format: article
Language:EN
Published: Nature Portfolio 2020
Subjects:
Q
Online Access:https://doaj.org/article/912f1b6a348d44e9b5cdb353e96d0eef
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