Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts
The direct conversion of carbon dioxide (CO2) using green hydrogen is a sustainable approach to jet fuel production. However, achieving a high level of performance remains a formidable challenge due to the inertness of CO2 and its low activity for subsequent C–C bond formation. In this study, we pre...
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Elsevier
2021
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oai:doaj.org-article:916fff25453a4959aed2972a28e730522021-11-28T04:39:12ZDirect conversion of CO2 to a jet fuel over CoFe alloy catalysts2666-675810.1016/j.xinn.2021.100170https://doaj.org/article/916fff25453a4959aed2972a28e730522021-11-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2666675821000953https://doaj.org/toc/2666-6758The direct conversion of carbon dioxide (CO2) using green hydrogen is a sustainable approach to jet fuel production. However, achieving a high level of performance remains a formidable challenge due to the inertness of CO2 and its low activity for subsequent C–C bond formation. In this study, we prepared a Na-modified CoFe alloy catalyst using layered double-hydroxide precursors that directly transforms CO2 to a jet fuel composed of C8–C16 jet-fuel-range hydrocarbons with very high selectivity. At a temperature of 240°C and pressure of 3 MPa, the catalyst achieves an unprecedentedly high C8–C16 selectivity of 63.5% with 10.2% CO2 conversion and a low combined selectivity of less than 22% toward undesired CO and CH4. Spectroscopic and computational studies show that the promotion of the coupling reaction between the carbon species and inhibition of the undesired CO2 methanation occur mainly due to the utilization of the CoFe alloy structure and addition of the Na promoter. This study provides a viable technique for the highly selective synthesis of eco-friendly and carbon-neutral jet fuel from CO2.Lei ZhangYaru DangXiaohong ZhouPeng GaoAlexander Petrus van BavelHao WangShenggang LiLei ShiYong YangEvgeny I. VovkYihao GaoYuhan SunElsevierarticlecarbon dioxide hydrogenationC–C couplingheterogeneous catalysisjet fuelCoFe alloysScience (General)Q1-390ENThe Innovation, Vol 2, Iss 4, Pp 100170- (2021) |
| institution |
DOAJ |
| collection |
DOAJ |
| language |
EN |
| topic |
carbon dioxide hydrogenation C–C coupling heterogeneous catalysis jet fuel CoFe alloys Science (General) Q1-390 |
| spellingShingle |
carbon dioxide hydrogenation C–C coupling heterogeneous catalysis jet fuel CoFe alloys Science (General) Q1-390 Lei Zhang Yaru Dang Xiaohong Zhou Peng Gao Alexander Petrus van Bavel Hao Wang Shenggang Li Lei Shi Yong Yang Evgeny I. Vovk Yihao Gao Yuhan Sun Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts |
| description |
The direct conversion of carbon dioxide (CO2) using green hydrogen is a sustainable approach to jet fuel production. However, achieving a high level of performance remains a formidable challenge due to the inertness of CO2 and its low activity for subsequent C–C bond formation. In this study, we prepared a Na-modified CoFe alloy catalyst using layered double-hydroxide precursors that directly transforms CO2 to a jet fuel composed of C8–C16 jet-fuel-range hydrocarbons with very high selectivity. At a temperature of 240°C and pressure of 3 MPa, the catalyst achieves an unprecedentedly high C8–C16 selectivity of 63.5% with 10.2% CO2 conversion and a low combined selectivity of less than 22% toward undesired CO and CH4. Spectroscopic and computational studies show that the promotion of the coupling reaction between the carbon species and inhibition of the undesired CO2 methanation occur mainly due to the utilization of the CoFe alloy structure and addition of the Na promoter. This study provides a viable technique for the highly selective synthesis of eco-friendly and carbon-neutral jet fuel from CO2. |
| format |
article |
| author |
Lei Zhang Yaru Dang Xiaohong Zhou Peng Gao Alexander Petrus van Bavel Hao Wang Shenggang Li Lei Shi Yong Yang Evgeny I. Vovk Yihao Gao Yuhan Sun |
| author_facet |
Lei Zhang Yaru Dang Xiaohong Zhou Peng Gao Alexander Petrus van Bavel Hao Wang Shenggang Li Lei Shi Yong Yang Evgeny I. Vovk Yihao Gao Yuhan Sun |
| author_sort |
Lei Zhang |
| title |
Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts |
| title_short |
Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts |
| title_full |
Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts |
| title_fullStr |
Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts |
| title_full_unstemmed |
Direct conversion of CO2 to a jet fuel over CoFe alloy catalysts |
| title_sort |
direct conversion of co2 to a jet fuel over cofe alloy catalysts |
| publisher |
Elsevier |
| publishDate |
2021 |
| url |
https://doaj.org/article/916fff25453a4959aed2972a28e73052 |
| work_keys_str_mv |
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| _version_ |
1718408272736681984 |