Upgrading ketone synthesis direct from carboxylic acids and organohalides

Due to their abundance and importance in organic chemistry, development of methods for ketone synthesis is essential. Here, the authors report a photoredox, nickel and phosphoranyl radical synergistic cross-electrophile coupling of aromatic acids and aryl/alkyl bromides to directly synthesise ketone...

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Autores principales: Rehanguli Ruzi, Kai Liu, Chengjian Zhu, Jin Xie
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/918a6d6aace14057b1822f8b673afe1c
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spelling oai:doaj.org-article:918a6d6aace14057b1822f8b673afe1c2021-12-02T16:10:52ZUpgrading ketone synthesis direct from carboxylic acids and organohalides10.1038/s41467-020-17224-22041-1723https://doaj.org/article/918a6d6aace14057b1822f8b673afe1c2020-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17224-2https://doaj.org/toc/2041-1723Due to their abundance and importance in organic chemistry, development of methods for ketone synthesis is essential. Here, the authors report a photoredox, nickel and phosphoranyl radical synergistic cross-electrophile coupling of aromatic acids and aryl/alkyl bromides to directly synthesise ketones.Rehanguli RuziKai LiuChengjian ZhuJin XieNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Rehanguli Ruzi
Kai Liu
Chengjian Zhu
Jin Xie
Upgrading ketone synthesis direct from carboxylic acids and organohalides
description Due to their abundance and importance in organic chemistry, development of methods for ketone synthesis is essential. Here, the authors report a photoredox, nickel and phosphoranyl radical synergistic cross-electrophile coupling of aromatic acids and aryl/alkyl bromides to directly synthesise ketones.
format article
author Rehanguli Ruzi
Kai Liu
Chengjian Zhu
Jin Xie
author_facet Rehanguli Ruzi
Kai Liu
Chengjian Zhu
Jin Xie
author_sort Rehanguli Ruzi
title Upgrading ketone synthesis direct from carboxylic acids and organohalides
title_short Upgrading ketone synthesis direct from carboxylic acids and organohalides
title_full Upgrading ketone synthesis direct from carboxylic acids and organohalides
title_fullStr Upgrading ketone synthesis direct from carboxylic acids and organohalides
title_full_unstemmed Upgrading ketone synthesis direct from carboxylic acids and organohalides
title_sort upgrading ketone synthesis direct from carboxylic acids and organohalides
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/918a6d6aace14057b1822f8b673afe1c
work_keys_str_mv AT rehanguliruzi upgradingketonesynthesisdirectfromcarboxylicacidsandorganohalides
AT kailiu upgradingketonesynthesisdirectfromcarboxylicacidsandorganohalides
AT chengjianzhu upgradingketonesynthesisdirectfromcarboxylicacidsandorganohalides
AT jinxie upgradingketonesynthesisdirectfromcarboxylicacidsandorganohalides
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