Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl

Nucleophilic alkylation of aromatics with main group reagents was achieved, but it is limited to a stoichiometric regime. Here, the authors report that the ytterbium(II) hydride reacts with ethene and propene to afford ytterbium(II) n-alkyls, both of which can facilitate the catalytic alkylation of...

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Auteurs principaux:	Georgia M. Richardson, Iskander Douair, Scott A. Cameron, Joe Bracegirdle, Robert A. Keyzers, Michael S. Hill, Laurent Maron, Mathew D. Anker
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2021
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/91910e60c3984a3bbbcd1c2f2c2fd8c2
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spelling	oai:doaj.org-article:91910e60c3984a3bbbcd1c2f2c2fd8c22021-12-02T15:49:48ZHydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl10.1038/s41467-021-23444-x2041-1723https://doaj.org/article/91910e60c3984a3bbbcd1c2f2c2fd8c22021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23444-xhttps://doaj.org/toc/2041-1723Nucleophilic alkylation of aromatics with main group reagents was achieved, but it is limited to a stoichiometric regime. Here, the authors report that the ytterbium(II) hydride reacts with ethene and propene to afford ytterbium(II) n-alkyls, both of which can facilitate the catalytic alkylation of benzene at room temperature via an SN2 mechanism.Georgia M. RichardsonIskander DouairScott A. CameronJoe BracegirdleRobert A. KeyzersMichael S. HillLaurent MaronMathew D. AnkerNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Georgia M. Richardson Iskander Douair Scott A. Cameron Joe Bracegirdle Robert A. Keyzers Michael S. Hill Laurent Maron Mathew D. Anker Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl
description	Nucleophilic alkylation of aromatics with main group reagents was achieved, but it is limited to a stoichiometric regime. Here, the authors report that the ytterbium(II) hydride reacts with ethene and propene to afford ytterbium(II) n-alkyls, both of which can facilitate the catalytic alkylation of benzene at room temperature via an SN2 mechanism.
format	article
author	Georgia M. Richardson Iskander Douair Scott A. Cameron Joe Bracegirdle Robert A. Keyzers Michael S. Hill Laurent Maron Mathew D. Anker
author_facet	Georgia M. Richardson Iskander Douair Scott A. Cameron Joe Bracegirdle Robert A. Keyzers Michael S. Hill Laurent Maron Mathew D. Anker
author_sort	Georgia M. Richardson
title	Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl
title_short	Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl
title_full	Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl
title_fullStr	Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl
title_full_unstemmed	Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl
title_sort	hydroarylation of olefins catalysed by a dimeric ytterbium(ii) alkyl
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/91910e60c3984a3bbbcd1c2f2c2fd8c2
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Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl

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