Photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst

Copper-based asymmetric photocatalysis has great synthetic potential, however it has been rarely exploited due to challenges inherent to such systems. Here, a chiral bisoxazoline copper catalyst is involved in a SET process, photoredox catalysis, Lewis acid activation and asymmetric induction to con...

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Autores principales:	Bowen Han, Yanjun Li, Ying Yu, Lei Gong
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/91d427fa74934f79918b1817fd700c5b
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spelling	oai:doaj.org-article:91d427fa74934f79918b1817fd700c5b2021-12-02T16:58:07ZPhotocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst10.1038/s41467-019-11688-72041-1723https://doaj.org/article/91d427fa74934f79918b1817fd700c5b2019-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11688-7https://doaj.org/toc/2041-1723Copper-based asymmetric photocatalysis has great synthetic potential, however it has been rarely exploited due to challenges inherent to such systems. Here, a chiral bisoxazoline copper catalyst is involved in a SET process, photoredox catalysis, Lewis acid activation and asymmetric induction to construct chiral vicinal diamines.Bowen HanYanjun LiYing YuLei GongNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Bowen Han Yanjun Li Ying Yu Lei Gong Photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst
description	Copper-based asymmetric photocatalysis has great synthetic potential, however it has been rarely exploited due to challenges inherent to such systems. Here, a chiral bisoxazoline copper catalyst is involved in a SET process, photoredox catalysis, Lewis acid activation and asymmetric induction to construct chiral vicinal diamines.
format	article
author	Bowen Han Yanjun Li Ying Yu Lei Gong
author_facet	Bowen Han Yanjun Li Ying Yu Lei Gong
author_sort	Bowen Han
title	Photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst
title_short	Photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst
title_full	Photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst
title_fullStr	Photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst
title_full_unstemmed	Photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst
title_sort	photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/91d427fa74934f79918b1817fd700c5b
work_keys_str_mv	AT bowenhan photocatalyticenantioselectiveaaminoalkylationofacycliciminederivativesbyachiralcoppercatalyst AT yanjunli photocatalyticenantioselectiveaaminoalkylationofacycliciminederivativesbyachiralcoppercatalyst AT yingyu photocatalyticenantioselectiveaaminoalkylationofacycliciminederivativesbyachiralcoppercatalyst AT leigong photocatalyticenantioselectiveaaminoalkylationofacycliciminederivativesbyachiralcoppercatalyst
_version_	1718382400888635392

Photocatalytic enantioselective α-aminoalkylation of acyclic imine derivatives by a chiral copper catalyst

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