The chemistry of branched condensed phosphates

The “anti-branching rule”, introduced in 1950, excludes branched polyphosphates from biological relevance due to their supposedly rapid hydrolysis. Here, the authors synthesize monodisperse branched polyphosphates and demonstrate their unexpected stability in water, as well as provide evidence for t...

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Autores principales: Tobias Dürr-Mayer, Danye Qiu, Verena B. Eisenbeis, Nicole Steck, Markus Häner, Alexandre Hofer, Andreas Mayer, Jay S. Siegel, Kim K. Baldridge, Henning J. Jessen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/921f9a2b1f1c438c80bc3a9744880a07
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Sumario:The “anti-branching rule”, introduced in 1950, excludes branched polyphosphates from biological relevance due to their supposedly rapid hydrolysis. Here, the authors synthesize monodisperse branched polyphosphates and demonstrate their unexpected stability in water, as well as provide evidence for their competence in phosphorylation.