Synthesis and characterization of Nd3+-Yb3+ doped hydroxyapatite nanoparticles
The present work focuses on Nd3+-Yb3+ co-doping of bare and Sr-substituted hydroxyapatite nanoparticles and their chemical, structural and optical characterization. An energy transfer between Nd3+ and Yb3+ centers was found, generating an efficient down-shifting process, where Nd3+ absorbs at a low...
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2021
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oai:doaj.org-article:923bc8351536442395942db3ba329f972021-11-28T04:37:45ZSynthesis and characterization of Nd3+-Yb3+ doped hydroxyapatite nanoparticles2590-147810.1016/j.omx.2021.100118https://doaj.org/article/923bc8351536442395942db3ba329f972021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2590147821000450https://doaj.org/toc/2590-1478The present work focuses on Nd3+-Yb3+ co-doping of bare and Sr-substituted hydroxyapatite nanoparticles and their chemical, structural and optical characterization. An energy transfer between Nd3+ and Yb3+ centers was found, generating an efficient down-shifting process, where Nd3+ absorbs at a low near-infrared wavelength and Yb3+ emits at its characteristic 2F7/2 → 2F5/2 transition. The energy transfer was found to be more efficient in Sr-substituted than in bare hydroxyapatite nanoparticles. The synthesized Nd3+-Yb3+ doped hydroxyapatite nanoparticles can potentially find applications not only as diagnostic near-infrared down-shifting agent but also as nanosystem for near-infrared photoactivated treatment.Marco Vittorio NardiMelanie TimpelEnrico BiondaniRiccardo CeccatoAndrea ChiappiniSandra DirèElsevierarticleHydroxyapatite nanoparticlesLanthanide dopingNd3+-Yb3+ energy transferDown-shiftingApplied optics. PhotonicsTA1501-1820Optics. LightQC350-467ENOptical Materials: X, Vol 12, Iss , Pp 100118- (2021) |
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DOAJ |
language |
EN |
topic |
Hydroxyapatite nanoparticles Lanthanide doping Nd3+-Yb3+ energy transfer Down-shifting Applied optics. Photonics TA1501-1820 Optics. Light QC350-467 |
spellingShingle |
Hydroxyapatite nanoparticles Lanthanide doping Nd3+-Yb3+ energy transfer Down-shifting Applied optics. Photonics TA1501-1820 Optics. Light QC350-467 Marco Vittorio Nardi Melanie Timpel Enrico Biondani Riccardo Ceccato Andrea Chiappini Sandra Dirè Synthesis and characterization of Nd3+-Yb3+ doped hydroxyapatite nanoparticles |
description |
The present work focuses on Nd3+-Yb3+ co-doping of bare and Sr-substituted hydroxyapatite nanoparticles and their chemical, structural and optical characterization. An energy transfer between Nd3+ and Yb3+ centers was found, generating an efficient down-shifting process, where Nd3+ absorbs at a low near-infrared wavelength and Yb3+ emits at its characteristic 2F7/2 → 2F5/2 transition. The energy transfer was found to be more efficient in Sr-substituted than in bare hydroxyapatite nanoparticles. The synthesized Nd3+-Yb3+ doped hydroxyapatite nanoparticles can potentially find applications not only as diagnostic near-infrared down-shifting agent but also as nanosystem for near-infrared photoactivated treatment. |
format |
article |
author |
Marco Vittorio Nardi Melanie Timpel Enrico Biondani Riccardo Ceccato Andrea Chiappini Sandra Dirè |
author_facet |
Marco Vittorio Nardi Melanie Timpel Enrico Biondani Riccardo Ceccato Andrea Chiappini Sandra Dirè |
author_sort |
Marco Vittorio Nardi |
title |
Synthesis and characterization of Nd3+-Yb3+ doped hydroxyapatite nanoparticles |
title_short |
Synthesis and characterization of Nd3+-Yb3+ doped hydroxyapatite nanoparticles |
title_full |
Synthesis and characterization of Nd3+-Yb3+ doped hydroxyapatite nanoparticles |
title_fullStr |
Synthesis and characterization of Nd3+-Yb3+ doped hydroxyapatite nanoparticles |
title_full_unstemmed |
Synthesis and characterization of Nd3+-Yb3+ doped hydroxyapatite nanoparticles |
title_sort |
synthesis and characterization of nd3+-yb3+ doped hydroxyapatite nanoparticles |
publisher |
Elsevier |
publishDate |
2021 |
url |
https://doaj.org/article/923bc8351536442395942db3ba329f97 |
work_keys_str_mv |
AT marcovittorionardi synthesisandcharacterizationofnd3yb3dopedhydroxyapatitenanoparticles AT melanietimpel synthesisandcharacterizationofnd3yb3dopedhydroxyapatitenanoparticles AT enricobiondani synthesisandcharacterizationofnd3yb3dopedhydroxyapatitenanoparticles AT riccardoceccato synthesisandcharacterizationofnd3yb3dopedhydroxyapatitenanoparticles AT andreachiappini synthesisandcharacterizationofnd3yb3dopedhydroxyapatitenanoparticles AT sandradire synthesisandcharacterizationofnd3yb3dopedhydroxyapatitenanoparticles |
_version_ |
1718408273540939776 |