Sargassum-Modified Asphalt: Effect of Particle Size on Its Physicochemical, Rheological, and Morphological Properties

The effect of sargassum particle size on the final properties of sargassum-modified asphalt is investigated in this article. Seaweed sargassum particles were first obtained and characterized through elemental analysis, thermogravimetric analysis (TGA), X-ray diffraction, and FTIR spectroscopy. Addit...

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Autores principales: Francisco Javier Escobar-Medina, José Luis Rivera-Armenta, Gabriel Hernández-Zamora, Beatriz Adriana Salazar-Cruz, Samuel Zapién-Castillo, Cynthia Graciela Flores-Hernández
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/92c8eec47ba94c888c616544e1de3e7f
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spelling oai:doaj.org-article:92c8eec47ba94c888c616544e1de3e7f2021-11-11T19:27:22ZSargassum-Modified Asphalt: Effect of Particle Size on Its Physicochemical, Rheological, and Morphological Properties10.3390/su1321117342071-1050https://doaj.org/article/92c8eec47ba94c888c616544e1de3e7f2021-10-01T00:00:00Zhttps://www.mdpi.com/2071-1050/13/21/11734https://doaj.org/toc/2071-1050The effect of sargassum particle size on the final properties of sargassum-modified asphalt is investigated in this article. Seaweed sargassum particles were first obtained and characterized through elemental analysis, thermogravimetric analysis (TGA), X-ray diffraction, and FTIR spectroscopy. Additionally, pure and sargassum-modified asphalt blends were evaluated through physical and rheological tests such as penetration, softening point, thermal stability, dynamic viscosity, failure temperature, and epifluorescence microscopy. Modified asphalt blends were prepared by the hot mixing technique using different proportions of sargassum particles of two maximum sizes: 500 μm and 850 μm. Incorporating 3.0 wt.% of sargassum particles under 500 μm into the asphalt increased the viscosity of the original binder by a factor of 2.5 and its complex modulus by a factor of 1.9. At the same time, its failure temperature was 11 °C higher than the reference asphalt, which implies an improved viscoelastic behavior and rutting resistance at high temperatures. The study results suggest that the particles under 500 μm were responsible for the most significant effect on the final properties of the asphalt. Moreover, the storage stability test revealed that the modified asphalt blends are stable when the sargassum particle content was kept below 3.0 wt.%. The statistical analysis of the effect of sargassum particle size and concentration on the modified asphalt properties revealed that the rheological behavior is more affected by the modifier particle size; in contrast, the conventional physical properties were more determined by its concentration. Therefore, using low proportions of fine sargassum particles is efficient for improving the physical and rheological properties of the original asphalt, which is not only positive from the asphalt modification technology point of view but also from a sustainable perspective, since seaweed sargassum has become a useless plague in many coastal regions.Francisco Javier Escobar-MedinaJosé Luis Rivera-ArmentaGabriel Hernández-ZamoraBeatriz Adriana Salazar-CruzSamuel Zapién-CastilloCynthia Graciela Flores-HernándezMDPI AGarticlesargassum-modified asphaltsize particle effectphysical testsrheological behaviorEnvironmental effects of industries and plantsTD194-195Renewable energy sourcesTJ807-830Environmental sciencesGE1-350ENSustainability, Vol 13, Iss 11734, p 11734 (2021)
institution DOAJ
collection DOAJ
language EN
topic sargassum-modified asphalt
size particle effect
physical tests
rheological behavior
Environmental effects of industries and plants
TD194-195
Renewable energy sources
TJ807-830
Environmental sciences
GE1-350
spellingShingle sargassum-modified asphalt
size particle effect
physical tests
rheological behavior
Environmental effects of industries and plants
TD194-195
Renewable energy sources
TJ807-830
Environmental sciences
GE1-350
Francisco Javier Escobar-Medina
José Luis Rivera-Armenta
Gabriel Hernández-Zamora
Beatriz Adriana Salazar-Cruz
Samuel Zapién-Castillo
Cynthia Graciela Flores-Hernández
Sargassum-Modified Asphalt: Effect of Particle Size on Its Physicochemical, Rheological, and Morphological Properties
description The effect of sargassum particle size on the final properties of sargassum-modified asphalt is investigated in this article. Seaweed sargassum particles were first obtained and characterized through elemental analysis, thermogravimetric analysis (TGA), X-ray diffraction, and FTIR spectroscopy. Additionally, pure and sargassum-modified asphalt blends were evaluated through physical and rheological tests such as penetration, softening point, thermal stability, dynamic viscosity, failure temperature, and epifluorescence microscopy. Modified asphalt blends were prepared by the hot mixing technique using different proportions of sargassum particles of two maximum sizes: 500 μm and 850 μm. Incorporating 3.0 wt.% of sargassum particles under 500 μm into the asphalt increased the viscosity of the original binder by a factor of 2.5 and its complex modulus by a factor of 1.9. At the same time, its failure temperature was 11 °C higher than the reference asphalt, which implies an improved viscoelastic behavior and rutting resistance at high temperatures. The study results suggest that the particles under 500 μm were responsible for the most significant effect on the final properties of the asphalt. Moreover, the storage stability test revealed that the modified asphalt blends are stable when the sargassum particle content was kept below 3.0 wt.%. The statistical analysis of the effect of sargassum particle size and concentration on the modified asphalt properties revealed that the rheological behavior is more affected by the modifier particle size; in contrast, the conventional physical properties were more determined by its concentration. Therefore, using low proportions of fine sargassum particles is efficient for improving the physical and rheological properties of the original asphalt, which is not only positive from the asphalt modification technology point of view but also from a sustainable perspective, since seaweed sargassum has become a useless plague in many coastal regions.
format article
author Francisco Javier Escobar-Medina
José Luis Rivera-Armenta
Gabriel Hernández-Zamora
Beatriz Adriana Salazar-Cruz
Samuel Zapién-Castillo
Cynthia Graciela Flores-Hernández
author_facet Francisco Javier Escobar-Medina
José Luis Rivera-Armenta
Gabriel Hernández-Zamora
Beatriz Adriana Salazar-Cruz
Samuel Zapién-Castillo
Cynthia Graciela Flores-Hernández
author_sort Francisco Javier Escobar-Medina
title Sargassum-Modified Asphalt: Effect of Particle Size on Its Physicochemical, Rheological, and Morphological Properties
title_short Sargassum-Modified Asphalt: Effect of Particle Size on Its Physicochemical, Rheological, and Morphological Properties
title_full Sargassum-Modified Asphalt: Effect of Particle Size on Its Physicochemical, Rheological, and Morphological Properties
title_fullStr Sargassum-Modified Asphalt: Effect of Particle Size on Its Physicochemical, Rheological, and Morphological Properties
title_full_unstemmed Sargassum-Modified Asphalt: Effect of Particle Size on Its Physicochemical, Rheological, and Morphological Properties
title_sort sargassum-modified asphalt: effect of particle size on its physicochemical, rheological, and morphological properties
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/92c8eec47ba94c888c616544e1de3e7f
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