Solubility of vitamin A in supercritical CO2: experimental study and thermodynamic modeling

Abstract One of the best methods of extracting Vitamin A, as a helper of the immune body system and vision, was measured in supercritical carbon dioxide (SC-CO2); Mole fractions were gained at practical conditions in which the temperature was in the range of 303–323 K and the pressure range was 90–2...

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Autores principales: Gowhar Ahmad Naikoo, Mohammad Saeedi Zadegan, Mona Zamani Pedram, Israr Ul Hassan, Waqar Ahmed, Golshan Yousefi Attar
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Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/92d4dab905eb48c9a4b6fd4a95622639
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spelling oai:doaj.org-article:92d4dab905eb48c9a4b6fd4a956226392021-12-02T14:53:43ZSolubility of vitamin A in supercritical CO2: experimental study and thermodynamic modeling10.1038/s41598-021-92374-x2045-2322https://doaj.org/article/92d4dab905eb48c9a4b6fd4a956226392021-08-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-92374-xhttps://doaj.org/toc/2045-2322Abstract One of the best methods of extracting Vitamin A, as a helper of the immune body system and vision, was measured in supercritical carbon dioxide (SC-CO2); Mole fractions were gained at practical conditions in which the temperature was in the range of 303–323 K and the pressure range was 90–235 bar, respectively. Moreover, four Equation of States [Soave–Redlich–Kwong, Peng–Robinson, Stryjek–Vera and Dashtizadeh–Pazuki–Taghikhani–Ghotbi (DPTG)] were compared with the experimental data. Also, the mixing rules of Van der Waals (vdW1 and vdW2) selected to correlate the solubility data of vitamin A. The outcomes indicate that each of EOSs coupled with vdW2, as a method of estimating the physicochemical and critical properties, were correlated with the solubility data of vitamin A in SC-CO2 with more accuracy, in comparison with vdW1. Among the cubic EOSs, the DPTG model with vdW2 generated the most suitable correlation with the percentage average absolute relative deviation (Average Absolute Relative Deviation%) of 6.Gowhar Ahmad NaikooMohammad Saeedi ZadeganMona Zamani PedramIsrar Ul HassanWaqar AhmedGolshan Yousefi AttarNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-13 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Gowhar Ahmad Naikoo
Mohammad Saeedi Zadegan
Mona Zamani Pedram
Israr Ul Hassan
Waqar Ahmed
Golshan Yousefi Attar
Solubility of vitamin A in supercritical CO2: experimental study and thermodynamic modeling
description Abstract One of the best methods of extracting Vitamin A, as a helper of the immune body system and vision, was measured in supercritical carbon dioxide (SC-CO2); Mole fractions were gained at practical conditions in which the temperature was in the range of 303–323 K and the pressure range was 90–235 bar, respectively. Moreover, four Equation of States [Soave–Redlich–Kwong, Peng–Robinson, Stryjek–Vera and Dashtizadeh–Pazuki–Taghikhani–Ghotbi (DPTG)] were compared with the experimental data. Also, the mixing rules of Van der Waals (vdW1 and vdW2) selected to correlate the solubility data of vitamin A. The outcomes indicate that each of EOSs coupled with vdW2, as a method of estimating the physicochemical and critical properties, were correlated with the solubility data of vitamin A in SC-CO2 with more accuracy, in comparison with vdW1. Among the cubic EOSs, the DPTG model with vdW2 generated the most suitable correlation with the percentage average absolute relative deviation (Average Absolute Relative Deviation%) of 6.
format article
author Gowhar Ahmad Naikoo
Mohammad Saeedi Zadegan
Mona Zamani Pedram
Israr Ul Hassan
Waqar Ahmed
Golshan Yousefi Attar
author_facet Gowhar Ahmad Naikoo
Mohammad Saeedi Zadegan
Mona Zamani Pedram
Israr Ul Hassan
Waqar Ahmed
Golshan Yousefi Attar
author_sort Gowhar Ahmad Naikoo
title Solubility of vitamin A in supercritical CO2: experimental study and thermodynamic modeling
title_short Solubility of vitamin A in supercritical CO2: experimental study and thermodynamic modeling
title_full Solubility of vitamin A in supercritical CO2: experimental study and thermodynamic modeling
title_fullStr Solubility of vitamin A in supercritical CO2: experimental study and thermodynamic modeling
title_full_unstemmed Solubility of vitamin A in supercritical CO2: experimental study and thermodynamic modeling
title_sort solubility of vitamin a in supercritical co2: experimental study and thermodynamic modeling
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/92d4dab905eb48c9a4b6fd4a95622639
work_keys_str_mv AT gowharahmadnaikoo solubilityofvitaminainsupercriticalco2experimentalstudyandthermodynamicmodeling
AT mohammadsaeedizadegan solubilityofvitaminainsupercriticalco2experimentalstudyandthermodynamicmodeling
AT monazamanipedram solubilityofvitaminainsupercriticalco2experimentalstudyandthermodynamicmodeling
AT israrulhassan solubilityofvitaminainsupercriticalco2experimentalstudyandthermodynamicmodeling
AT waqarahmed solubilityofvitaminainsupercriticalco2experimentalstudyandthermodynamicmodeling
AT golshanyousefiattar solubilityofvitaminainsupercriticalco2experimentalstudyandthermodynamicmodeling
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