Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating
Polymer coatings containing thermal blocking and near-infrared (NIR)-reflective pigments have received much attention for their potential applications in energy-saving fields. A drawback of these coatings is sustainability providing similar long-term performance. Surface cleaning is mandatory to rem...
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MDPI AG
2021
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oai:doaj.org-article:933ed30d341540368fe46dfbf397364f2021-11-25T18:30:17ZUniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating10.3390/nano111128452079-4991https://doaj.org/article/933ed30d341540368fe46dfbf397364f2021-10-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/2845https://doaj.org/toc/2079-4991Polymer coatings containing thermal blocking and near-infrared (NIR)-reflective pigments have received much attention for their potential applications in energy-saving fields. A drawback of these coatings is sustainability providing similar long-term performance. Surface cleaning is mandatory to remove contaminants that decrease reflectance. In this study, synthesized hollow titania as photocatalyst was used to impart anti-contamination to infrared (IR)-reflective coatings. A TiO<sub>2</sub> shell was selectively formed on an anionic polystyrene core, modified by methacrylic acid. According to sintering temperature, the enhancement of light absorption ability and photocatalytic activity as methyl orange decomposition was observed with phase composition change. The methylene blue decomposition reaction, reflectance measurement, and measuring thermal profiling of coated steel confirmed the manifestation of hollow particles to dust degradation characteristics and the enhancement of reflection and thermal shielding.Tae Ho YunChangyong YimMDPI AGarticletitaniahollow structurephotocatalystanti contaminationIR reflective coatingChemistryQD1-999ENNanomaterials, Vol 11, Iss 2845, p 2845 (2021) |
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titania hollow structure photocatalyst anti contamination IR reflective coating Chemistry QD1-999 |
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titania hollow structure photocatalyst anti contamination IR reflective coating Chemistry QD1-999 Tae Ho Yun Changyong Yim Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating |
description |
Polymer coatings containing thermal blocking and near-infrared (NIR)-reflective pigments have received much attention for their potential applications in energy-saving fields. A drawback of these coatings is sustainability providing similar long-term performance. Surface cleaning is mandatory to remove contaminants that decrease reflectance. In this study, synthesized hollow titania as photocatalyst was used to impart anti-contamination to infrared (IR)-reflective coatings. A TiO<sub>2</sub> shell was selectively formed on an anionic polystyrene core, modified by methacrylic acid. According to sintering temperature, the enhancement of light absorption ability and photocatalytic activity as methyl orange decomposition was observed with phase composition change. The methylene blue decomposition reaction, reflectance measurement, and measuring thermal profiling of coated steel confirmed the manifestation of hollow particles to dust degradation characteristics and the enhancement of reflection and thermal shielding. |
format |
article |
author |
Tae Ho Yun Changyong Yim |
author_facet |
Tae Ho Yun Changyong Yim |
author_sort |
Tae Ho Yun |
title |
Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating |
title_short |
Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating |
title_full |
Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating |
title_fullStr |
Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating |
title_full_unstemmed |
Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating |
title_sort |
uniform fabrication of hollow titania using anionic modified acrylated polymer template for phase composition effect as photocatalyst and infrared reflective coating |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/933ed30d341540368fe46dfbf397364f |
work_keys_str_mv |
AT taehoyun uniformfabricationofhollowtitaniausinganionicmodifiedacrylatedpolymertemplateforphasecompositioneffectasphotocatalystandinfraredreflectivecoating AT changyongyim uniformfabricationofhollowtitaniausinganionicmodifiedacrylatedpolymertemplateforphasecompositioneffectasphotocatalystandinfraredreflectivecoating |
_version_ |
1718411091355107328 |