Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating

Polymer coatings containing thermal blocking and near-infrared (NIR)-reflective pigments have received much attention for their potential applications in energy-saving fields. A drawback of these coatings is sustainability providing similar long-term performance. Surface cleaning is mandatory to rem...

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Autores principales: Tae Ho Yun, Changyong Yim
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Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/933ed30d341540368fe46dfbf397364f
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spelling oai:doaj.org-article:933ed30d341540368fe46dfbf397364f2021-11-25T18:30:17ZUniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating10.3390/nano111128452079-4991https://doaj.org/article/933ed30d341540368fe46dfbf397364f2021-10-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/2845https://doaj.org/toc/2079-4991Polymer coatings containing thermal blocking and near-infrared (NIR)-reflective pigments have received much attention for their potential applications in energy-saving fields. A drawback of these coatings is sustainability providing similar long-term performance. Surface cleaning is mandatory to remove contaminants that decrease reflectance. In this study, synthesized hollow titania as photocatalyst was used to impart anti-contamination to infrared (IR)-reflective coatings. A TiO<sub>2</sub> shell was selectively formed on an anionic polystyrene core, modified by methacrylic acid. According to sintering temperature, the enhancement of light absorption ability and photocatalytic activity as methyl orange decomposition was observed with phase composition change. The methylene blue decomposition reaction, reflectance measurement, and measuring thermal profiling of coated steel confirmed the manifestation of hollow particles to dust degradation characteristics and the enhancement of reflection and thermal shielding.Tae Ho YunChangyong YimMDPI AGarticletitaniahollow structurephotocatalystanti contaminationIR reflective coatingChemistryQD1-999ENNanomaterials, Vol 11, Iss 2845, p 2845 (2021)
institution DOAJ
collection DOAJ
language EN
topic titania
hollow structure
photocatalyst
anti contamination
IR reflective coating
Chemistry
QD1-999
spellingShingle titania
hollow structure
photocatalyst
anti contamination
IR reflective coating
Chemistry
QD1-999
Tae Ho Yun
Changyong Yim
Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating
description Polymer coatings containing thermal blocking and near-infrared (NIR)-reflective pigments have received much attention for their potential applications in energy-saving fields. A drawback of these coatings is sustainability providing similar long-term performance. Surface cleaning is mandatory to remove contaminants that decrease reflectance. In this study, synthesized hollow titania as photocatalyst was used to impart anti-contamination to infrared (IR)-reflective coatings. A TiO<sub>2</sub> shell was selectively formed on an anionic polystyrene core, modified by methacrylic acid. According to sintering temperature, the enhancement of light absorption ability and photocatalytic activity as methyl orange decomposition was observed with phase composition change. The methylene blue decomposition reaction, reflectance measurement, and measuring thermal profiling of coated steel confirmed the manifestation of hollow particles to dust degradation characteristics and the enhancement of reflection and thermal shielding.
format article
author Tae Ho Yun
Changyong Yim
author_facet Tae Ho Yun
Changyong Yim
author_sort Tae Ho Yun
title Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating
title_short Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating
title_full Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating
title_fullStr Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating
title_full_unstemmed Uniform Fabrication of Hollow Titania Using Anionic Modified Acrylated Polymer Template for Phase Composition Effect as Photocatalyst and Infrared Reflective Coating
title_sort uniform fabrication of hollow titania using anionic modified acrylated polymer template for phase composition effect as photocatalyst and infrared reflective coating
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/933ed30d341540368fe46dfbf397364f
work_keys_str_mv AT taehoyun uniformfabricationofhollowtitaniausinganionicmodifiedacrylatedpolymertemplateforphasecompositioneffectasphotocatalystandinfraredreflectivecoating
AT changyongyim uniformfabricationofhollowtitaniausinganionicmodifiedacrylatedpolymertemplateforphasecompositioneffectasphotocatalystandinfraredreflectivecoating
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