NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY

Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordina...

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Autores principales:	BASSENE SEYDOU, SEMBENE BOYE MOUHAMADOU, SIDIBE MAMADOU, DIOP LIBASSE
Formato:	article
Lenguaje:	EN
Publicado:	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2020
Materias:	bridging anion discrete or two metallic components structures electrostatic interactions octahedral or trigonal bipyramidal environments Technology T Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/938f2f3d939f40b7b5717c9c723a7b36
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spelling	oai:doaj.org-article:938f2f3d939f40b7b5717c9c723a7b362021-12-02T18:36:10ZNEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY10.29081/jesr.v26i1.22068-75592344-4932https://doaj.org/article/938f2f3d939f40b7b5717c9c723a7b362020-01-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/2https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordinating ligand, the environments around the tin (IV) centers being octahedral or trigonal bipyramidal. In Me4N(SnPh2)2(H2PO2)2Cl3 and Cl2Sn(H2PO2)2NMe4H2PO2, the cation is involved in electrostatic interactions with the anions. BASSENE SEYDOUSEMBENE BOYE MOUHAMADOUSIDIBE MAMADOUDIOP LIBASSEAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticlebridging aniondiscrete or two metallic components structureselectrostatic interactionsoctahedral or trigonal bipyramidal environmentsTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 26, Iss 1 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	bridging anion discrete or two metallic components structures electrostatic interactions octahedral or trigonal bipyramidal environments Technology T Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	bridging anion discrete or two metallic components structures electrostatic interactions octahedral or trigonal bipyramidal environments Technology T Engineering (General). Civil engineering (General) TA1-2040 BASSENE SEYDOU SEMBENE BOYE MOUHAMADOU SIDIBE MAMADOU DIOP LIBASSE NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
description	Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordinating ligand, the environments around the tin (IV) centers being octahedral or trigonal bipyramidal. In Me4N(SnPh2)2(H2PO2)2Cl3 and Cl2Sn(H2PO2)2NMe4H2PO2, the cation is involved in electrostatic interactions with the anions.
format	article
author	BASSENE SEYDOU SEMBENE BOYE MOUHAMADOU SIDIBE MAMADOU DIOP LIBASSE
author_facet	BASSENE SEYDOU SEMBENE BOYE MOUHAMADOU SIDIBE MAMADOU DIOP LIBASSE
author_sort	BASSENE SEYDOU
title	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_short	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_full	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_fullStr	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_full_unstemmed	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_sort	new phosphinato organo- and halotin(iv) derivatives, adducts and complexes: synthesis and spectroscopic study
publisher	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
publishDate	2020
url	https://doaj.org/article/938f2f3d939f40b7b5717c9c723a7b36
work_keys_str_mv	AT basseneseydou newphosphinatoorganoandhalotinivderivativesadductsandcomplexessynthesisandspectroscopicstudy AT sembeneboyemouhamadou newphosphinatoorganoandhalotinivderivativesadductsandcomplexessynthesisandspectroscopicstudy AT sidibemamadou newphosphinatoorganoandhalotinivderivativesadductsandcomplexessynthesisandspectroscopicstudy AT dioplibasse newphosphinatoorganoandhalotinivderivativesadductsandcomplexessynthesisandspectroscopicstudy
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NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY

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