Highly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures

Due to the low ring strain and facile dimerization, ring-opening metathesis polymerization of cyclopentadiene, readily obtainable from petroleum feedstock, has not been realized. Here the authors show an ultrarapidly initiating trifluoromethanesulfonamide-based ruthenium catalyst enables it at low t...

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Autores principales:	Kitaek Song, Kunsoon Kim, Daeun Hong, Jungwon Kim, Chae Eun Heo, Hugh I. Kim, Soon Hyeok Hong
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/93a31acd77704ab1ad8312a2cb9499ef
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spelling	oai:doaj.org-article:93a31acd77704ab1ad8312a2cb9499ef2021-12-02T16:57:51ZHighly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures10.1038/s41467-019-11806-52041-1723https://doaj.org/article/93a31acd77704ab1ad8312a2cb9499ef2019-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11806-5https://doaj.org/toc/2041-1723Due to the low ring strain and facile dimerization, ring-opening metathesis polymerization of cyclopentadiene, readily obtainable from petroleum feedstock, has not been realized. Here the authors show an ultrarapidly initiating trifluoromethanesulfonamide-based ruthenium catalyst enables it at low temperatures.Kitaek SongKunsoon KimDaeun HongJungwon KimChae Eun HeoHugh I. KimSoon Hyeok HongNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Kitaek Song Kunsoon Kim Daeun Hong Jungwon Kim Chae Eun Heo Hugh I. Kim Soon Hyeok Hong Highly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures
description	Due to the low ring strain and facile dimerization, ring-opening metathesis polymerization of cyclopentadiene, readily obtainable from petroleum feedstock, has not been realized. Here the authors show an ultrarapidly initiating trifluoromethanesulfonamide-based ruthenium catalyst enables it at low temperatures.
format	article
author	Kitaek Song Kunsoon Kim Daeun Hong Jungwon Kim Chae Eun Heo Hugh I. Kim Soon Hyeok Hong
author_facet	Kitaek Song Kunsoon Kim Daeun Hong Jungwon Kim Chae Eun Heo Hugh I. Kim Soon Hyeok Hong
author_sort	Kitaek Song
title	Highly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures
title_short	Highly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures
title_full	Highly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures
title_fullStr	Highly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures
title_full_unstemmed	Highly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures
title_sort	highly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/93a31acd77704ab1ad8312a2cb9499ef
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Highly active ruthenium metathesis catalysts enabling ring-opening metathesis polymerization of cyclopentadiene at low temperatures

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