Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation
Olefins are employed in many coupling procedures but direct hydrocarbonations of unactivated olefins remain to be developed. Here, the authors report the nickel-catalyzed reductive coupling of olefins with aryl and alky electrophiles under mild conditions and with a broad substrate scope.
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Nature Portfolio
2016
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oai:doaj.org-article:93b07284e1f74b9ba0ea3f6d171714992021-12-02T17:32:20ZPractical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation10.1038/ncomms111292041-1723https://doaj.org/article/93b07284e1f74b9ba0ea3f6d171714992016-04-01T00:00:00Zhttps://doi.org/10.1038/ncomms11129https://doaj.org/toc/2041-1723Olefins are employed in many coupling procedures but direct hydrocarbonations of unactivated olefins remain to be developed. Here, the authors report the nickel-catalyzed reductive coupling of olefins with aryl and alky electrophiles under mild conditions and with a broad substrate scope.Xi LuBin XiaoZhenqi ZhangTianjun GongWei SuJun YiYao FuLei LiuNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016) |
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Science Q Xi Lu Bin Xiao Zhenqi Zhang Tianjun Gong Wei Su Jun Yi Yao Fu Lei Liu Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
description |
Olefins are employed in many coupling procedures but direct hydrocarbonations of unactivated olefins remain to be developed. Here, the authors report the nickel-catalyzed reductive coupling of olefins with aryl and alky electrophiles under mild conditions and with a broad substrate scope. |
format |
article |
author |
Xi Lu Bin Xiao Zhenqi Zhang Tianjun Gong Wei Su Jun Yi Yao Fu Lei Liu |
author_facet |
Xi Lu Bin Xiao Zhenqi Zhang Tianjun Gong Wei Su Jun Yi Yao Fu Lei Liu |
author_sort |
Xi Lu |
title |
Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
title_short |
Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
title_full |
Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
title_fullStr |
Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
title_full_unstemmed |
Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
title_sort |
practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
publisher |
Nature Portfolio |
publishDate |
2016 |
url |
https://doaj.org/article/93b07284e1f74b9ba0ea3f6d17171499 |
work_keys_str_mv |
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1718380320810598400 |