Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes

Control of regioselectivity in the double hydroboration of dienes to obtain a single organoboron compound is a considerable synthetic challenge. Here, the authors show a cobalt-catalyzed chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes with regioselective control.

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Detalles Bibliográficos
Autores principales: Ming Hu, Shaozhong Ge
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Q
Acceso en línea:https://doaj.org/article/93c4f49d9de242c38b2a63f6d9a7f062
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Sumario:Control of regioselectivity in the double hydroboration of dienes to obtain a single organoboron compound is a considerable synthetic challenge. Here, the authors show a cobalt-catalyzed chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes with regioselective control.