Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes
Control of regioselectivity in the double hydroboration of dienes to obtain a single organoboron compound is a considerable synthetic challenge. Here, the authors show a cobalt-catalyzed chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes with regioselective control.
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Auteurs principaux: | , |
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Format: | article |
Langue: | EN |
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Nature Portfolio
2020
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Accès en ligne: | https://doaj.org/article/93c4f49d9de242c38b2a63f6d9a7f062 |
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Résumé: | Control of regioselectivity in the double hydroboration of dienes to obtain a single organoboron compound is a considerable synthetic challenge. Here, the authors show a cobalt-catalyzed chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes with regioselective control. |
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