Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes

Control of regioselectivity in the double hydroboration of dienes to obtain a single organoboron compound is a considerable synthetic challenge. Here, the authors show a cobalt-catalyzed chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes with regioselective control.

Enregistré dans:
Détails bibliographiques
Auteurs principaux: Ming Hu, Shaozhong Ge
Format: article
Langue:EN
Publié: Nature Portfolio 2020
Sujets:
Q
Accès en ligne:https://doaj.org/article/93c4f49d9de242c38b2a63f6d9a7f062
Tags: Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
Description
Résumé:Control of regioselectivity in the double hydroboration of dienes to obtain a single organoboron compound is a considerable synthetic challenge. Here, the authors show a cobalt-catalyzed chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes with regioselective control.