Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes

Control of regioselectivity in the double hydroboration of dienes to obtain a single organoboron compound is a considerable synthetic challenge. Here, the authors show a cobalt-catalyzed chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes with regioselective control.

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Auteurs principaux:	Ming Hu, Shaozhong Ge
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2020
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/93c4f49d9de242c38b2a63f6d9a7f062
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spelling	oai:doaj.org-article:93c4f49d9de242c38b2a63f6d9a7f0622021-12-02T16:49:16ZVersatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes10.1038/s41467-020-14543-22041-1723https://doaj.org/article/93c4f49d9de242c38b2a63f6d9a7f0622020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14543-2https://doaj.org/toc/2041-1723Control of regioselectivity in the double hydroboration of dienes to obtain a single organoboron compound is a considerable synthetic challenge. Here, the authors show a cobalt-catalyzed chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes with regioselective control.Ming HuShaozhong GeNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Ming Hu Shaozhong Ge Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes
description	Control of regioselectivity in the double hydroboration of dienes to obtain a single organoboron compound is a considerable synthetic challenge. Here, the authors show a cobalt-catalyzed chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes with regioselective control.
format	article
author	Ming Hu Shaozhong Ge
author_facet	Ming Hu Shaozhong Ge
author_sort	Ming Hu
title	Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes
title_short	Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes
title_full	Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes
title_fullStr	Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes
title_full_unstemmed	Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes
title_sort	versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/93c4f49d9de242c38b2a63f6d9a7f062
work_keys_str_mv	AT minghu versatilecobaltcatalyzedregioselectivechainwalkingdoublehydroborationof1ndienestoaccessgembisborylalkanes AT shaozhongge versatilecobaltcatalyzedregioselectivechainwalkingdoublehydroborationof1ndienestoaccessgembisborylalkanes
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Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes

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