Role of orbitally degenerate Mn(III) ions in magnetic bistability of Mn5-cyanide cluster: new prospects for design of single molecule magnets with high blocking temperatures

Role of orbitally degenerate Mn(III) ions in magnetic bistability of Mn5-cyanide cluster: new prospects for design of single molecule magnets with high blocking temperatures

In this paper we report a new model aimed at the explanation of the magnetic properties of the trigonal bipyramidal cyanide cluster - [MnII (tmphen)2]3[MnIII (CN)6]2} (tmphen = 4,5,7,8-tetramethyl-1,10-phenantroline). The model explicitly takes into account the strong single-ion...

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Detalles Bibliográficos
Autores principales: Barba, Doina, Antonova, Natalia, Butorov, Ivan, Bodrug, Nicolae, Calancea, Valentin, Coşciug, Ion
Formato: article
Lenguaje:EN
Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2011
Materias:
Physics
QC1-999
Electronics
TK7800-8360
Acceso en línea:https://doaj.org/article/93f4da0119774b678c813314e2ced204
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