Crystalline functionalized endohedral C60 metallofullerides

While endohedral metallofullerenes have demonstrated advantageous electronic and magnetic properties, the isolation of monomeric M@C60 remains highly challenging. Here, the authors prepare trifluoromethylated Gd@C60 and La@C60, where the functionalization of C60 allows for the stabilization of these...

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Autores principales: Ayano Nakagawa, Makiko Nishino, Hiroyuki Niwa, Katsuma Ishino, Zhiyong Wang, Haruka Omachi, Ko Furukawa, Takahisa Yamaguchi, Tatsuhisa Kato, Shunji Bandow, Jeremy Rio, Chris Ewels, Shinobu Aoyagi, Hisanori Shinohara
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Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/941fe21500694600a1b74936afb16454
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spelling oai:doaj.org-article:941fe21500694600a1b74936afb164542021-12-02T15:34:38ZCrystalline functionalized endohedral C60 metallofullerides10.1038/s41467-018-05496-82041-1723https://doaj.org/article/941fe21500694600a1b74936afb164542018-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05496-8https://doaj.org/toc/2041-1723While endohedral metallofullerenes have demonstrated advantageous electronic and magnetic properties, the isolation of monomeric M@C60 remains highly challenging. Here, the authors prepare trifluoromethylated Gd@C60 and La@C60, where the functionalization of C60 allows for the stabilization of these otherwise reactive species.Ayano NakagawaMakiko NishinoHiroyuki NiwaKatsuma IshinoZhiyong WangHaruka OmachiKo FurukawaTakahisa YamaguchiTatsuhisa KatoShunji BandowJeremy RioChris EwelsShinobu AoyagiHisanori ShinoharaNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Ayano Nakagawa
Makiko Nishino
Hiroyuki Niwa
Katsuma Ishino
Zhiyong Wang
Haruka Omachi
Ko Furukawa
Takahisa Yamaguchi
Tatsuhisa Kato
Shunji Bandow
Jeremy Rio
Chris Ewels
Shinobu Aoyagi
Hisanori Shinohara
Crystalline functionalized endohedral C60 metallofullerides
description While endohedral metallofullerenes have demonstrated advantageous electronic and magnetic properties, the isolation of monomeric M@C60 remains highly challenging. Here, the authors prepare trifluoromethylated Gd@C60 and La@C60, where the functionalization of C60 allows for the stabilization of these otherwise reactive species.
format article
author Ayano Nakagawa
Makiko Nishino
Hiroyuki Niwa
Katsuma Ishino
Zhiyong Wang
Haruka Omachi
Ko Furukawa
Takahisa Yamaguchi
Tatsuhisa Kato
Shunji Bandow
Jeremy Rio
Chris Ewels
Shinobu Aoyagi
Hisanori Shinohara
author_facet Ayano Nakagawa
Makiko Nishino
Hiroyuki Niwa
Katsuma Ishino
Zhiyong Wang
Haruka Omachi
Ko Furukawa
Takahisa Yamaguchi
Tatsuhisa Kato
Shunji Bandow
Jeremy Rio
Chris Ewels
Shinobu Aoyagi
Hisanori Shinohara
author_sort Ayano Nakagawa
title Crystalline functionalized endohedral C60 metallofullerides
title_short Crystalline functionalized endohedral C60 metallofullerides
title_full Crystalline functionalized endohedral C60 metallofullerides
title_fullStr Crystalline functionalized endohedral C60 metallofullerides
title_full_unstemmed Crystalline functionalized endohedral C60 metallofullerides
title_sort crystalline functionalized endohedral c60 metallofullerides
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/941fe21500694600a1b74936afb16454
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