Variable combinations of organophosphines in PtP3X derivatives: Structural aspects

This review covers over fifty Pt (II) complexes of the compositions PtP3X (X = H, OL, NL, BL, Cl, SL, Br, or I). These complexes crystallized in three crystal classes: monoclinic (23 examples) triclinic (17 examples) and orthorhombic (11 examples). The PtP3Cl is most common with 23 examples. There a...

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Autores principales:	Melník Milan, Mikuš Peter
Formato:	article
Lenguaje:	EN
Publicado:	De Gruyter 2021
Materias:	structure organophosphines ptp3x trans-influence Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/94953dae5a9b496d9e070f61fe54457c
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spelling	oai:doaj.org-article:94953dae5a9b496d9e070f61fe54457c2021-12-05T14:10:55ZVariable combinations of organophosphines in PtP3X derivatives: Structural aspects2191-021910.1515/mgmc-2021-0003https://doaj.org/article/94953dae5a9b496d9e070f61fe54457c2021-01-01T00:00:00Zhttps://doi.org/10.1515/mgmc-2021-0003https://doaj.org/toc/2191-0219This review covers over fifty Pt (II) complexes of the compositions PtP3X (X = H, OL, NL, BL, Cl, SL, Br, or I). These complexes crystallized in three crystal classes: monoclinic (23 examples) triclinic (17 examples) and orthorhombic (11 examples). The PtP3Cl is most common with 23 examples. There are variable combinations of organophosphines monodentate – P; bidentate- P,P; P,N; P,B; and tridentate – P,P,P; P,O,P; P,N,P; and P,S,P. The structural parameters (Pt–L, L–Pt–L) are analyzed and discussed with an attention to the distortion of a square-planar geometry about the Pt (II) atoms as well as of trans-influence. The sums of Pt–L (x4) bond distances growing with covalent radius of the X-atoms.Melník MilanMikuš PeterDe Gruyterarticlestructureorganophosphinesptp3xtrans-influenceChemistryQD1-999ENMain Group Metal Chemistry, Vol 44, Iss 1, Pp 12-21 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	structure organophosphines ptp3x trans-influence Chemistry QD1-999
spellingShingle	structure organophosphines ptp3x trans-influence Chemistry QD1-999 Melník Milan Mikuš Peter Variable combinations of organophosphines in PtP3X derivatives: Structural aspects
description	This review covers over fifty Pt (II) complexes of the compositions PtP3X (X = H, OL, NL, BL, Cl, SL, Br, or I). These complexes crystallized in three crystal classes: monoclinic (23 examples) triclinic (17 examples) and orthorhombic (11 examples). The PtP3Cl is most common with 23 examples. There are variable combinations of organophosphines monodentate – P; bidentate- P,P; P,N; P,B; and tridentate – P,P,P; P,O,P; P,N,P; and P,S,P. The structural parameters (Pt–L, L–Pt–L) are analyzed and discussed with an attention to the distortion of a square-planar geometry about the Pt (II) atoms as well as of trans-influence. The sums of Pt–L (x4) bond distances growing with covalent radius of the X-atoms.
format	article
author	Melník Milan Mikuš Peter
author_facet	Melník Milan Mikuš Peter
author_sort	Melník Milan
title	Variable combinations of organophosphines in PtP3X derivatives: Structural aspects
title_short	Variable combinations of organophosphines in PtP3X derivatives: Structural aspects
title_full	Variable combinations of organophosphines in PtP3X derivatives: Structural aspects
title_fullStr	Variable combinations of organophosphines in PtP3X derivatives: Structural aspects
title_full_unstemmed	Variable combinations of organophosphines in PtP3X derivatives: Structural aspects
title_sort	variable combinations of organophosphines in ptp3x derivatives: structural aspects
publisher	De Gruyter
publishDate	2021
url	https://doaj.org/article/94953dae5a9b496d9e070f61fe54457c
work_keys_str_mv	AT melnikmilan variablecombinationsoforganophosphinesinptp3xderivativesstructuralaspects AT mikuspeter variablecombinationsoforganophosphinesinptp3xderivativesstructuralaspects
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Variable combinations of organophosphines in PtP3X derivatives: Structural aspects

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