Plasma synthesis and treatment of copper-based nanopowders

Cu-based nanoparticles with different morphologies were prepared via submerged elec- trical discharge of bulk copper and graphite electrodes in a CuCl2 aqueous solution. The synthesized material was subjected to laser-induced modification. The influence of discharge parameters and electrode compos...

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Autores principales: Tarasenko, N., Nevar, A., Savastenko, N., Grigorieva, T.
Formato: article
Lenguaje:EN
Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2010
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Acceso en línea:https://doaj.org/article/94d194d1e9ed4ef3b46cf900fe836ed2
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Sumario:Cu-based nanoparticles with different morphologies were prepared via submerged elec- trical discharge of bulk copper and graphite electrodes in a CuCl2 aqueous solution. The synthesized material was subjected to laser-induced modification. The influence of discharge parameters and electrode composition on the morphology and composition of final products were investigated by transmission electron microscopy (TEM), X-ray difractometry (XRD), and UV-Vis spectroscopy. It was found that core-shell nanoparticles were formed by the treatment of a CuCl2 aqueous solution by the arc pulsed discharge with a pulse duration of 4 ms and a peak current of 10 A. Irradiation of nanoparticles in an aqueous solution by a pulsed Nd:YAG laser at 532 nm was shown to cause the shape change and size reduction of the particles. The possible formation mechanism of Cu-based nanoparticles is proposed.