Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols
Construction of C–S bonds via C–H functionalization is an attractive route to organosulfur compounds. Here, the authors show the synergistic combination of NiH-catalysed alkene isomerization and subsequent thiolation to afford remote hydrothiolation products from alkenes (or alkynes) and thiols unde...
Guardado en:
Autores principales: | , , |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2019
|
Materias: | |
Acceso en línea: | https://doaj.org/article/954cd38c9e4b48aa9b17020e43fde7b9 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
id |
oai:doaj.org-article:954cd38c9e4b48aa9b17020e43fde7b9 |
---|---|
record_format |
dspace |
spelling |
oai:doaj.org-article:954cd38c9e4b48aa9b17020e43fde7b92021-12-02T16:57:30ZNickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols10.1038/s41467-019-09783-w2041-1723https://doaj.org/article/954cd38c9e4b48aa9b17020e43fde7b92019-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09783-whttps://doaj.org/toc/2041-1723Construction of C–S bonds via C–H functionalization is an attractive route to organosulfur compounds. Here, the authors show the synergistic combination of NiH-catalysed alkene isomerization and subsequent thiolation to afford remote hydrothiolation products from alkenes (or alkynes) and thiols under mild conditions.Yulong ZhangXianfeng XuShaolin ZhuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019) |
institution |
DOAJ |
collection |
DOAJ |
language |
EN |
topic |
Science Q |
spellingShingle |
Science Q Yulong Zhang Xianfeng Xu Shaolin Zhu Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols |
description |
Construction of C–S bonds via C–H functionalization is an attractive route to organosulfur compounds. Here, the authors show the synergistic combination of NiH-catalysed alkene isomerization and subsequent thiolation to afford remote hydrothiolation products from alkenes (or alkynes) and thiols under mild conditions. |
format |
article |
author |
Yulong Zhang Xianfeng Xu Shaolin Zhu |
author_facet |
Yulong Zhang Xianfeng Xu Shaolin Zhu |
author_sort |
Yulong Zhang |
title |
Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols |
title_short |
Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols |
title_full |
Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols |
title_fullStr |
Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols |
title_full_unstemmed |
Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols |
title_sort |
nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/954cd38c9e4b48aa9b17020e43fde7b9 |
work_keys_str_mv |
AT yulongzhang nickelcatalysedselectivemigratoryhydrothiolationofalkenesandalkyneswiththiols AT xianfengxu nickelcatalysedselectivemigratoryhydrothiolationofalkenesandalkyneswiththiols AT shaolinzhu nickelcatalysedselectivemigratoryhydrothiolationofalkenesandalkyneswiththiols |
_version_ |
1718382515007258624 |