Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols

Construction of C–S bonds via C–H functionalization is an attractive route to organosulfur compounds. Here, the authors show the synergistic combination of NiH-catalysed alkene isomerization and subsequent thiolation to afford remote hydrothiolation products from alkenes (or alkynes) and thiols unde...

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Autores principales: Yulong Zhang, Xianfeng Xu, Shaolin Zhu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/954cd38c9e4b48aa9b17020e43fde7b9
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spelling oai:doaj.org-article:954cd38c9e4b48aa9b17020e43fde7b92021-12-02T16:57:30ZNickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols10.1038/s41467-019-09783-w2041-1723https://doaj.org/article/954cd38c9e4b48aa9b17020e43fde7b92019-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09783-whttps://doaj.org/toc/2041-1723Construction of C–S bonds via C–H functionalization is an attractive route to organosulfur compounds. Here, the authors show the synergistic combination of NiH-catalysed alkene isomerization and subsequent thiolation to afford remote hydrothiolation products from alkenes (or alkynes) and thiols under mild conditions.Yulong ZhangXianfeng XuShaolin ZhuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yulong Zhang
Xianfeng Xu
Shaolin Zhu
Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols
description Construction of C–S bonds via C–H functionalization is an attractive route to organosulfur compounds. Here, the authors show the synergistic combination of NiH-catalysed alkene isomerization and subsequent thiolation to afford remote hydrothiolation products from alkenes (or alkynes) and thiols under mild conditions.
format article
author Yulong Zhang
Xianfeng Xu
Shaolin Zhu
author_facet Yulong Zhang
Xianfeng Xu
Shaolin Zhu
author_sort Yulong Zhang
title Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols
title_short Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols
title_full Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols
title_fullStr Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols
title_full_unstemmed Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols
title_sort nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/954cd38c9e4b48aa9b17020e43fde7b9
work_keys_str_mv AT yulongzhang nickelcatalysedselectivemigratoryhydrothiolationofalkenesandalkyneswiththiols
AT xianfengxu nickelcatalysedselectivemigratoryhydrothiolationofalkenesandalkyneswiththiols
AT shaolinzhu nickelcatalysedselectivemigratoryhydrothiolationofalkenesandalkyneswiththiols
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