Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework

Oxygen capture is attractive for catalysis, sensing, and separations, but engineering stable and selective adsorbents is challenging. Here the authors combine metal-based electron transfer with secondary coordination sphere effects in a metal-organic framework, leading to strong and reversible O2 ad...

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Autores principales:	Julia Oktawiec, Henry Z. H. Jiang, Jenny G. Vitillo, Douglas A. Reed, Lucy E. Darago, Benjamin A. Trump, Varinia Bernales, Harriet Li, Kristen A. Colwell, Hiroyasu Furukawa, Craig M. Brown, Laura Gagliardi, Jeffrey R. Long
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/95971025db63432eb25b0d9df76d92af
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spelling	oai:doaj.org-article:95971025db63432eb25b0d9df76d92af2021-12-02T17:23:25ZNegative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework10.1038/s41467-020-16897-z2041-1723https://doaj.org/article/95971025db63432eb25b0d9df76d92af2020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16897-zhttps://doaj.org/toc/2041-1723Oxygen capture is attractive for catalysis, sensing, and separations, but engineering stable and selective adsorbents is challenging. Here the authors combine metal-based electron transfer with secondary coordination sphere effects in a metal-organic framework, leading to strong and reversible O2 adsorption that also exhibits negative cooperativity.Julia OktawiecHenry Z. H. JiangJenny G. VitilloDouglas A. ReedLucy E. DaragoBenjamin A. TrumpVarinia BernalesHarriet LiKristen A. ColwellHiroyasu FurukawaCraig M. BrownLaura GagliardiJeffrey R. LongNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Julia Oktawiec Henry Z. H. Jiang Jenny G. Vitillo Douglas A. Reed Lucy E. Darago Benjamin A. Trump Varinia Bernales Harriet Li Kristen A. Colwell Hiroyasu Furukawa Craig M. Brown Laura Gagliardi Jeffrey R. Long Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework
description	Oxygen capture is attractive for catalysis, sensing, and separations, but engineering stable and selective adsorbents is challenging. Here the authors combine metal-based electron transfer with secondary coordination sphere effects in a metal-organic framework, leading to strong and reversible O2 adsorption that also exhibits negative cooperativity.
format	article
author	Julia Oktawiec Henry Z. H. Jiang Jenny G. Vitillo Douglas A. Reed Lucy E. Darago Benjamin A. Trump Varinia Bernales Harriet Li Kristen A. Colwell Hiroyasu Furukawa Craig M. Brown Laura Gagliardi Jeffrey R. Long
author_facet	Julia Oktawiec Henry Z. H. Jiang Jenny G. Vitillo Douglas A. Reed Lucy E. Darago Benjamin A. Trump Varinia Bernales Harriet Li Kristen A. Colwell Hiroyasu Furukawa Craig M. Brown Laura Gagliardi Jeffrey R. Long
author_sort	Julia Oktawiec
title	Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework
title_short	Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework
title_full	Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework
title_fullStr	Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework
title_full_unstemmed	Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework
title_sort	negative cooperativity upon hydrogen bond-stabilized o2 adsorption in a redox-active metal–organic framework
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/95971025db63432eb25b0d9df76d92af
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Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework

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