A Comparison of Uric Acid Optical Detection Using as Sensitive Materials an Amino-Substituted Porphyrin and Its Nanomaterials with CuNPs, PtNPs and Pt@CuNPs

Hybrid nanomaterials consisting in 5,10,15,20-tetrakis(4-amino-phenyl)-porphyrin (TAmPP) and copper nanoparticles (CuNPs), platinum nanoparticles (PtNPs), or both types (Pt@CuNPs) were obtained and tested for their capacity to optically detect uric acid from solutions. The introduction of diverse me...

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Autores principales: Camelia Epuran, Ion Fratilescu, Diana Anghel, Mihaela Birdeanu, Corina Orha, Eugenia Fagadar-Cosma
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Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/95b949186a58480491808756789a4648
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spelling oai:doaj.org-article:95b949186a58480491808756789a46482021-11-25T18:52:00ZA Comparison of Uric Acid Optical Detection Using as Sensitive Materials an Amino-Substituted Porphyrin and Its Nanomaterials with CuNPs, PtNPs and Pt@CuNPs10.3390/pr91120722227-9717https://doaj.org/article/95b949186a58480491808756789a46482021-11-01T00:00:00Zhttps://www.mdpi.com/2227-9717/9/11/2072https://doaj.org/toc/2227-9717Hybrid nanomaterials consisting in 5,10,15,20-tetrakis(4-amino-phenyl)-porphyrin (TAmPP) and copper nanoparticles (CuNPs), platinum nanoparticles (PtNPs), or both types (Pt@CuNPs) were obtained and tested for their capacity to optically detect uric acid from solutions. The introduction of diverse metal nanoparticles into the hybrid material proved their capacity to improve the detection range. The detection was monitored by using UV-Vis spectrophotometry, and differences between morphology of the materials were performed using atomic force microscopy (AFM). The hybrid material formed between porphyrin and PtNPs hasthe best and most stable response for uric acid detection in the range of 6.1958 × 10<sup>−6</sup>–1.5763 × 10<sup>−5</sup> M, even in the presence of very high concentrations of the interference species present in human environment.Camelia EpuranIon FratilescuDiana AnghelMihaela BirdeanuCorina OrhaEugenia Fagadar-CosmaMDPI AGarticleuric acid detectionPtNPsCuNPsPt@CuNPsamino-substituted porphyrinhybrid porphyrin nanomaterialsChemical technologyTP1-1185ChemistryQD1-999ENProcesses, Vol 9, Iss 2072, p 2072 (2021)
institution DOAJ
collection DOAJ
language EN
topic uric acid detection
PtNPs
CuNPs
Pt@CuNPs
amino-substituted porphyrin
hybrid porphyrin nanomaterials
Chemical technology
TP1-1185
Chemistry
QD1-999
spellingShingle uric acid detection
PtNPs
CuNPs
Pt@CuNPs
amino-substituted porphyrin
hybrid porphyrin nanomaterials
Chemical technology
TP1-1185
Chemistry
QD1-999
Camelia Epuran
Ion Fratilescu
Diana Anghel
Mihaela Birdeanu
Corina Orha
Eugenia Fagadar-Cosma
A Comparison of Uric Acid Optical Detection Using as Sensitive Materials an Amino-Substituted Porphyrin and Its Nanomaterials with CuNPs, PtNPs and Pt@CuNPs
description Hybrid nanomaterials consisting in 5,10,15,20-tetrakis(4-amino-phenyl)-porphyrin (TAmPP) and copper nanoparticles (CuNPs), platinum nanoparticles (PtNPs), or both types (Pt@CuNPs) were obtained and tested for their capacity to optically detect uric acid from solutions. The introduction of diverse metal nanoparticles into the hybrid material proved their capacity to improve the detection range. The detection was monitored by using UV-Vis spectrophotometry, and differences between morphology of the materials were performed using atomic force microscopy (AFM). The hybrid material formed between porphyrin and PtNPs hasthe best and most stable response for uric acid detection in the range of 6.1958 × 10<sup>−6</sup>–1.5763 × 10<sup>−5</sup> M, even in the presence of very high concentrations of the interference species present in human environment.
format article
author Camelia Epuran
Ion Fratilescu
Diana Anghel
Mihaela Birdeanu
Corina Orha
Eugenia Fagadar-Cosma
author_facet Camelia Epuran
Ion Fratilescu
Diana Anghel
Mihaela Birdeanu
Corina Orha
Eugenia Fagadar-Cosma
author_sort Camelia Epuran
title A Comparison of Uric Acid Optical Detection Using as Sensitive Materials an Amino-Substituted Porphyrin and Its Nanomaterials with CuNPs, PtNPs and Pt@CuNPs
title_short A Comparison of Uric Acid Optical Detection Using as Sensitive Materials an Amino-Substituted Porphyrin and Its Nanomaterials with CuNPs, PtNPs and Pt@CuNPs
title_full A Comparison of Uric Acid Optical Detection Using as Sensitive Materials an Amino-Substituted Porphyrin and Its Nanomaterials with CuNPs, PtNPs and Pt@CuNPs
title_fullStr A Comparison of Uric Acid Optical Detection Using as Sensitive Materials an Amino-Substituted Porphyrin and Its Nanomaterials with CuNPs, PtNPs and Pt@CuNPs
title_full_unstemmed A Comparison of Uric Acid Optical Detection Using as Sensitive Materials an Amino-Substituted Porphyrin and Its Nanomaterials with CuNPs, PtNPs and Pt@CuNPs
title_sort comparison of uric acid optical detection using as sensitive materials an amino-substituted porphyrin and its nanomaterials with cunps, ptnps and pt@cunps
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/95b949186a58480491808756789a4648
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