Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors
Abstract In bilayers of two-dimensional semiconductors with stacking arrangements which lack inversion symmetry charge transfer between the layers due to layer-asymmetric interband hybridisation can generate a potential difference between the layers. We analyse bilayers of transition metal dichalcog...
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Nature Portfolio
2021
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oai:doaj.org-article:95ed22c8fc954ba38e1e87a671e68c282021-12-02T18:18:51ZWeak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors10.1038/s41598-021-92710-12045-2322https://doaj.org/article/95ed22c8fc954ba38e1e87a671e68c282021-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-92710-1https://doaj.org/toc/2045-2322Abstract In bilayers of two-dimensional semiconductors with stacking arrangements which lack inversion symmetry charge transfer between the layers due to layer-asymmetric interband hybridisation can generate a potential difference between the layers. We analyse bilayers of transition metal dichalcogenides (TMDs)—in particular, $$\hbox {WSe}_2$$ WSe 2 —for which we find a substantial stacking-dependent charge transfer, and InSe, for which the charge transfer is found to be negligibly small. The information obtained about TMDs is then used to map potentials generated by the interlayer charge transfer across the moiré superlattice in twistronic bilayers.Fábio FerreiraVladimir V. EnaldievVladimir I. Fal’koSamuel J. MagorrianNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-10 (2021) |
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Medicine R Science Q Fábio Ferreira Vladimir V. Enaldiev Vladimir I. Fal’ko Samuel J. Magorrian Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors |
description |
Abstract In bilayers of two-dimensional semiconductors with stacking arrangements which lack inversion symmetry charge transfer between the layers due to layer-asymmetric interband hybridisation can generate a potential difference between the layers. We analyse bilayers of transition metal dichalcogenides (TMDs)—in particular, $$\hbox {WSe}_2$$ WSe 2 —for which we find a substantial stacking-dependent charge transfer, and InSe, for which the charge transfer is found to be negligibly small. The information obtained about TMDs is then used to map potentials generated by the interlayer charge transfer across the moiré superlattice in twistronic bilayers. |
format |
article |
author |
Fábio Ferreira Vladimir V. Enaldiev Vladimir I. Fal’ko Samuel J. Magorrian |
author_facet |
Fábio Ferreira Vladimir V. Enaldiev Vladimir I. Fal’ko Samuel J. Magorrian |
author_sort |
Fábio Ferreira |
title |
Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors |
title_short |
Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors |
title_full |
Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors |
title_fullStr |
Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors |
title_full_unstemmed |
Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors |
title_sort |
weak ferroelectric charge transfer in layer-asymmetric bilayers of 2d semiconductors |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/95ed22c8fc954ba38e1e87a671e68c28 |
work_keys_str_mv |
AT fabioferreira weakferroelectricchargetransferinlayerasymmetricbilayersof2dsemiconductors AT vladimirvenaldiev weakferroelectricchargetransferinlayerasymmetricbilayersof2dsemiconductors AT vladimirifalko weakferroelectricchargetransferinlayerasymmetricbilayersof2dsemiconductors AT samueljmagorrian weakferroelectricchargetransferinlayerasymmetricbilayersof2dsemiconductors |
_version_ |
1718378170156056576 |