Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors

Abstract In bilayers of two-dimensional semiconductors with stacking arrangements which lack inversion symmetry charge transfer between the layers due to layer-asymmetric interband hybridisation can generate a potential difference between the layers. We analyse bilayers of transition metal dichalcog...

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Autores principales: Fábio Ferreira, Vladimir V. Enaldiev, Vladimir I. Fal’ko, Samuel J. Magorrian
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Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/95ed22c8fc954ba38e1e87a671e68c28
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spelling oai:doaj.org-article:95ed22c8fc954ba38e1e87a671e68c282021-12-02T18:18:51ZWeak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors10.1038/s41598-021-92710-12045-2322https://doaj.org/article/95ed22c8fc954ba38e1e87a671e68c282021-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-92710-1https://doaj.org/toc/2045-2322Abstract In bilayers of two-dimensional semiconductors with stacking arrangements which lack inversion symmetry charge transfer between the layers due to layer-asymmetric interband hybridisation can generate a potential difference between the layers. We analyse bilayers of transition metal dichalcogenides (TMDs)—in particular, $$\hbox {WSe}_2$$ WSe 2 —for which we find a substantial stacking-dependent charge transfer, and InSe, for which the charge transfer is found to be negligibly small. The information obtained about TMDs is then used to map potentials generated by the interlayer charge transfer across the moiré superlattice in twistronic bilayers.Fábio FerreiraVladimir V. EnaldievVladimir I. Fal’koSamuel J. MagorrianNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-10 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Fábio Ferreira
Vladimir V. Enaldiev
Vladimir I. Fal’ko
Samuel J. Magorrian
Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors
description Abstract In bilayers of two-dimensional semiconductors with stacking arrangements which lack inversion symmetry charge transfer between the layers due to layer-asymmetric interband hybridisation can generate a potential difference between the layers. We analyse bilayers of transition metal dichalcogenides (TMDs)—in particular, $$\hbox {WSe}_2$$ WSe 2 —for which we find a substantial stacking-dependent charge transfer, and InSe, for which the charge transfer is found to be negligibly small. The information obtained about TMDs is then used to map potentials generated by the interlayer charge transfer across the moiré superlattice in twistronic bilayers.
format article
author Fábio Ferreira
Vladimir V. Enaldiev
Vladimir I. Fal’ko
Samuel J. Magorrian
author_facet Fábio Ferreira
Vladimir V. Enaldiev
Vladimir I. Fal’ko
Samuel J. Magorrian
author_sort Fábio Ferreira
title Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors
title_short Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors
title_full Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors
title_fullStr Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors
title_full_unstemmed Weak ferroelectric charge transfer in layer-asymmetric bilayers of 2D semiconductors
title_sort weak ferroelectric charge transfer in layer-asymmetric bilayers of 2d semiconductors
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/95ed22c8fc954ba38e1e87a671e68c28
work_keys_str_mv AT fabioferreira weakferroelectricchargetransferinlayerasymmetricbilayersof2dsemiconductors
AT vladimirvenaldiev weakferroelectricchargetransferinlayerasymmetricbilayersof2dsemiconductors
AT vladimirifalko weakferroelectricchargetransferinlayerasymmetricbilayersof2dsemiconductors
AT samueljmagorrian weakferroelectricchargetransferinlayerasymmetricbilayersof2dsemiconductors
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