Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates
The Rauhut-Currier reaction is a powerful method to form carbon-carbon bonds. Here, the authors report an enantioselective intramolecular variant between alkenes and allenoates, giving access to highly functionalised bicyclic lactones in excellent enantiomeric excess.
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Nature Portfolio
2016
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oai:doaj.org-article:95f6805f00ea4ad29c2ae5238fbe9be22021-12-02T16:57:02ZEnantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates10.1038/ncomms130242041-1723https://doaj.org/article/95f6805f00ea4ad29c2ae5238fbe9be22016-10-01T00:00:00Zhttps://doi.org/10.1038/ncomms13024https://doaj.org/toc/2041-1723The Rauhut-Currier reaction is a powerful method to form carbon-carbon bonds. Here, the authors report an enantioselective intramolecular variant between alkenes and allenoates, giving access to highly functionalised bicyclic lactones in excellent enantiomeric excess.Weijun YaoXiaowei DouShan WenJi’en WuJagadese J. VittalYixin LuNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016) |
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Science Q Weijun Yao Xiaowei Dou Shan Wen Ji’en Wu Jagadese J. Vittal Yixin Lu Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates |
description |
The Rauhut-Currier reaction is a powerful method to form carbon-carbon bonds. Here, the authors report an enantioselective intramolecular variant between alkenes and allenoates, giving access to highly functionalised bicyclic lactones in excellent enantiomeric excess. |
format |
article |
author |
Weijun Yao Xiaowei Dou Shan Wen Ji’en Wu Jagadese J. Vittal Yixin Lu |
author_facet |
Weijun Yao Xiaowei Dou Shan Wen Ji’en Wu Jagadese J. Vittal Yixin Lu |
author_sort |
Weijun Yao |
title |
Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates |
title_short |
Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates |
title_full |
Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates |
title_fullStr |
Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates |
title_full_unstemmed |
Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates |
title_sort |
enantioselective desymmetrization of cyclohexadienones via an intramolecular rauhut–currier reaction of allenoates |
publisher |
Nature Portfolio |
publishDate |
2016 |
url |
https://doaj.org/article/95f6805f00ea4ad29c2ae5238fbe9be2 |
work_keys_str_mv |
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1718382636916801536 |