Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates

The Rauhut-Currier reaction is a powerful method to form carbon-carbon bonds. Here, the authors report an enantioselective intramolecular variant between alkenes and allenoates, giving access to highly functionalised bicyclic lactones in excellent enantiomeric excess.

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Autores principales: Weijun Yao, Xiaowei Dou, Shan Wen, Ji’en Wu, Jagadese J. Vittal, Yixin Lu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/95f6805f00ea4ad29c2ae5238fbe9be2
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spelling oai:doaj.org-article:95f6805f00ea4ad29c2ae5238fbe9be22021-12-02T16:57:02ZEnantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates10.1038/ncomms130242041-1723https://doaj.org/article/95f6805f00ea4ad29c2ae5238fbe9be22016-10-01T00:00:00Zhttps://doi.org/10.1038/ncomms13024https://doaj.org/toc/2041-1723The Rauhut-Currier reaction is a powerful method to form carbon-carbon bonds. Here, the authors report an enantioselective intramolecular variant between alkenes and allenoates, giving access to highly functionalised bicyclic lactones in excellent enantiomeric excess.Weijun YaoXiaowei DouShan WenJi’en WuJagadese J. VittalYixin LuNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Weijun Yao
Xiaowei Dou
Shan Wen
Ji’en Wu
Jagadese J. Vittal
Yixin Lu
Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates
description The Rauhut-Currier reaction is a powerful method to form carbon-carbon bonds. Here, the authors report an enantioselective intramolecular variant between alkenes and allenoates, giving access to highly functionalised bicyclic lactones in excellent enantiomeric excess.
format article
author Weijun Yao
Xiaowei Dou
Shan Wen
Ji’en Wu
Jagadese J. Vittal
Yixin Lu
author_facet Weijun Yao
Xiaowei Dou
Shan Wen
Ji’en Wu
Jagadese J. Vittal
Yixin Lu
author_sort Weijun Yao
title Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates
title_short Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates
title_full Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates
title_fullStr Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates
title_full_unstemmed Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates
title_sort enantioselective desymmetrization of cyclohexadienones via an intramolecular rauhut–currier reaction of allenoates
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/95f6805f00ea4ad29c2ae5238fbe9be2
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AT xiaoweidou enantioselectivedesymmetrizationofcyclohexadienonesviaanintramolecularrauhutcurrierreactionofallenoates
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