Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates

The Rauhut-Currier reaction is a powerful method to form carbon-carbon bonds. Here, the authors report an enantioselective intramolecular variant between alkenes and allenoates, giving access to highly functionalised bicyclic lactones in excellent enantiomeric excess.

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Auteurs principaux: Weijun Yao, Xiaowei Dou, Shan Wen, Ji’en Wu, Jagadese J. Vittal, Yixin Lu
Format: article
Langue:EN
Publié: Nature Portfolio 2016
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Accès en ligne:https://doaj.org/article/95f6805f00ea4ad29c2ae5238fbe9be2
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