Chemical engineering of quasicrystal approximants in lanthanide-based coordination solids

Tessellation of self-assembling molecular building blocks is attractive for accessing metal-organic materials with geometric frustration, however such motifs are rare. Here the authors use ytterbium(II) as a five-vertex node to assemble an Archimedean tessellation in a bulk, molecule-based material.

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Detalles Bibliográficos
Autores principales: Laura Voigt, Mariusz Kubus, Kasper S. Pedersen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/96286803a7574f4581fdaf8b7bcdc0b7
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Sumario:Tessellation of self-assembling molecular building blocks is attractive for accessing metal-organic materials with geometric frustration, however such motifs are rare. Here the authors use ytterbium(II) as a five-vertex node to assemble an Archimedean tessellation in a bulk, molecule-based material.