Optimization of the Composition of Silicone Enamel by the Taguchi Method Using Surfactants Obtained from Oil Refining Waste

The aim of this work is to optimize the composition of a two-component silicone enamel consisting of an aluminum pigment and a polyphenylsiloxane polymer to obtain the maximum dispersion of the pigment in the coating. The following products were used as surfactants: AS-1, PEPA, and Telaz. To assess...

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Autores principales:	Vitaliy Tyukanko, Alexandr Demyanenko, Antonina Dyuryagina, Kirill Ostrovnoy, Marianna Lezhneva
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	dispersion surfactants silicones polyorganosiloxanes composition optimization Taguchi method Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/9653fe74bb774d949f148600ddde9f06
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spelling	oai:doaj.org-article:9653fe74bb774d949f148600ddde9f062021-11-11T18:41:46ZOptimization of the Composition of Silicone Enamel by the Taguchi Method Using Surfactants Obtained from Oil Refining Waste10.3390/polym132136192073-4360https://doaj.org/article/9653fe74bb774d949f148600ddde9f062021-10-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/21/3619https://doaj.org/toc/2073-4360The aim of this work is to optimize the composition of a two-component silicone enamel consisting of an aluminum pigment and a polyphenylsiloxane polymer to obtain the maximum dispersion of the pigment in the coating. The following products were used as surfactants: AS-1, PEPA, and Telaz. To assess the effect of surfactants on the dispersion of the pigment, computer-optical microscopy was used. The results of the studies showed that all the studied surfactants cause an improvement in the dispersion of the pigment. According to the degree of influence on the dispersion of the pigment, surfactants can be arranged in a row: PEPA > Telaz > AS-1. When the PEPA content in the enamel is 0.25 g/dm<sup>3</sup>, a decrease in the diameter of the pigment particles by 46% (from 26 to 14 microns) is recorded, with an increase in their specific amount by 2 times (from 258 to 550 pcs). Optimal enamel compositions allow a reduction in the corrosion rate by 11 times (from 0.6 to 0.053 mm/year) and improvement to the decorative properties of coatings (roughness, gloss, etc.). The effectiveness of the AS-1 product (obtained from oil refining waste) as a dispersant additive in silicone enamel has been proven.Vitaliy TyukankoAlexandr DemyanenkoAntonina DyuryaginaKirill OstrovnoyMarianna LezhnevaMDPI AGarticledispersionsurfactantssiliconespolyorganosiloxanescomposition optimizationTaguchi methodOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3619, p 3619 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	dispersion surfactants silicones polyorganosiloxanes composition optimization Taguchi method Organic chemistry QD241-441
spellingShingle	dispersion surfactants silicones polyorganosiloxanes composition optimization Taguchi method Organic chemistry QD241-441 Vitaliy Tyukanko Alexandr Demyanenko Antonina Dyuryagina Kirill Ostrovnoy Marianna Lezhneva Optimization of the Composition of Silicone Enamel by the Taguchi Method Using Surfactants Obtained from Oil Refining Waste
description	The aim of this work is to optimize the composition of a two-component silicone enamel consisting of an aluminum pigment and a polyphenylsiloxane polymer to obtain the maximum dispersion of the pigment in the coating. The following products were used as surfactants: AS-1, PEPA, and Telaz. To assess the effect of surfactants on the dispersion of the pigment, computer-optical microscopy was used. The results of the studies showed that all the studied surfactants cause an improvement in the dispersion of the pigment. According to the degree of influence on the dispersion of the pigment, surfactants can be arranged in a row: PEPA > Telaz > AS-1. When the PEPA content in the enamel is 0.25 g/dm<sup>3</sup>, a decrease in the diameter of the pigment particles by 46% (from 26 to 14 microns) is recorded, with an increase in their specific amount by 2 times (from 258 to 550 pcs). Optimal enamel compositions allow a reduction in the corrosion rate by 11 times (from 0.6 to 0.053 mm/year) and improvement to the decorative properties of coatings (roughness, gloss, etc.). The effectiveness of the AS-1 product (obtained from oil refining waste) as a dispersant additive in silicone enamel has been proven.
format	article
author	Vitaliy Tyukanko Alexandr Demyanenko Antonina Dyuryagina Kirill Ostrovnoy Marianna Lezhneva
author_facet	Vitaliy Tyukanko Alexandr Demyanenko Antonina Dyuryagina Kirill Ostrovnoy Marianna Lezhneva
author_sort	Vitaliy Tyukanko
title	Optimization of the Composition of Silicone Enamel by the Taguchi Method Using Surfactants Obtained from Oil Refining Waste
title_short	Optimization of the Composition of Silicone Enamel by the Taguchi Method Using Surfactants Obtained from Oil Refining Waste
title_full	Optimization of the Composition of Silicone Enamel by the Taguchi Method Using Surfactants Obtained from Oil Refining Waste
title_fullStr	Optimization of the Composition of Silicone Enamel by the Taguchi Method Using Surfactants Obtained from Oil Refining Waste
title_full_unstemmed	Optimization of the Composition of Silicone Enamel by the Taguchi Method Using Surfactants Obtained from Oil Refining Waste
title_sort	optimization of the composition of silicone enamel by the taguchi method using surfactants obtained from oil refining waste
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/9653fe74bb774d949f148600ddde9f06
work_keys_str_mv	AT vitaliytyukanko optimizationofthecompositionofsiliconeenamelbythetaguchimethodusingsurfactantsobtainedfromoilrefiningwaste AT alexandrdemyanenko optimizationofthecompositionofsiliconeenamelbythetaguchimethodusingsurfactantsobtainedfromoilrefiningwaste AT antoninadyuryagina optimizationofthecompositionofsiliconeenamelbythetaguchimethodusingsurfactantsobtainedfromoilrefiningwaste AT kirillostrovnoy optimizationofthecompositionofsiliconeenamelbythetaguchimethodusingsurfactantsobtainedfromoilrefiningwaste AT mariannalezhneva optimizationofthecompositionofsiliconeenamelbythetaguchimethodusingsurfactantsobtainedfromoilrefiningwaste
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Optimization of the Composition of Silicone Enamel by the Taguchi Method Using Surfactants Obtained from Oil Refining Waste

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