Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides

Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides

Catalysis involving Au(I)/Au(III) cycles are notoriously hampered by the reluctance of Au(I) towards oxidative addition. Here, the authors show that an hemilabile bidentate ligand promotes oxidative addition of aryl halides to Au(I) and the catalytic formation of biaryl coupling products.

Saved in:
Bibliographic Details
Main Authors: Abdallah Zeineddine, Laura Estévez, Sonia Mallet-Ladeira, Karinne Miqueu, Abderrahmane Amgoune, Didier Bourissou
Format: article
Language:EN
Published: Nature Portfolio 2017
Subjects:
Science
Q
Online Access:https://doaj.org/article/9659d77298bc497e9ccba56e9cd11a8d
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Catalysis involving Au(I)/Au(III) cycles are notoriously hampered by the reluctance of Au(I) towards oxidative addition. Here, the authors show that an hemilabile bidentate ligand promotes oxidative addition of aryl halides to Au(I) and the catalytic formation of biaryl coupling products.

Similar Items