Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides
Catalysis involving Au(I)/Au(III) cycles are notoriously hampered by the reluctance of Au(I) towards oxidative addition. Here, the authors show that an hemilabile bidentate ligand promotes oxidative addition of aryl halides to Au(I) and the catalytic formation of biaryl coupling products.
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Nature Portfolio
2017
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oai:doaj.org-article:9659d77298bc497e9ccba56e9cd11a8d2021-12-02T14:41:20ZRational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides10.1038/s41467-017-00672-82041-1723https://doaj.org/article/9659d77298bc497e9ccba56e9cd11a8d2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00672-8https://doaj.org/toc/2041-1723Catalysis involving Au(I)/Au(III) cycles are notoriously hampered by the reluctance of Au(I) towards oxidative addition. Here, the authors show that an hemilabile bidentate ligand promotes oxidative addition of aryl halides to Au(I) and the catalytic formation of biaryl coupling products.Abdallah ZeineddineLaura EstévezSonia Mallet-LadeiraKarinne MiqueuAbderrahmane AmgouneDidier BourissouNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017) |
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Science Q Abdallah Zeineddine Laura Estévez Sonia Mallet-Ladeira Karinne Miqueu Abderrahmane Amgoune Didier Bourissou Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides |
description |
Catalysis involving Au(I)/Au(III) cycles are notoriously hampered by the reluctance of Au(I) towards oxidative addition. Here, the authors show that an hemilabile bidentate ligand promotes oxidative addition of aryl halides to Au(I) and the catalytic formation of biaryl coupling products. |
format |
article |
author |
Abdallah Zeineddine Laura Estévez Sonia Mallet-Ladeira Karinne Miqueu Abderrahmane Amgoune Didier Bourissou |
author_facet |
Abdallah Zeineddine Laura Estévez Sonia Mallet-Ladeira Karinne Miqueu Abderrahmane Amgoune Didier Bourissou |
author_sort |
Abdallah Zeineddine |
title |
Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides |
title_short |
Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides |
title_full |
Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides |
title_fullStr |
Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides |
title_full_unstemmed |
Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides |
title_sort |
rational development of catalytic au(i)/au(iii) arylation involving mild oxidative addition of aryl halides |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/9659d77298bc497e9ccba56e9cd11a8d |
work_keys_str_mv |
AT abdallahzeineddine rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides AT lauraestevez rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides AT soniamalletladeira rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides AT karinnemiqueu rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides AT abderrahmaneamgoune rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides AT didierbourissou rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides |
_version_ |
1718389945930874880 |