Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides

Catalysis involving Au(I)/Au(III) cycles are notoriously hampered by the reluctance of Au(I) towards oxidative addition. Here, the authors show that an hemilabile bidentate ligand promotes oxidative addition of aryl halides to Au(I) and the catalytic formation of biaryl coupling products.

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Autores principales: Abdallah Zeineddine, Laura Estévez, Sonia Mallet-Ladeira, Karinne Miqueu, Abderrahmane Amgoune, Didier Bourissou
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/9659d77298bc497e9ccba56e9cd11a8d
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spelling oai:doaj.org-article:9659d77298bc497e9ccba56e9cd11a8d2021-12-02T14:41:20ZRational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides10.1038/s41467-017-00672-82041-1723https://doaj.org/article/9659d77298bc497e9ccba56e9cd11a8d2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00672-8https://doaj.org/toc/2041-1723Catalysis involving Au(I)/Au(III) cycles are notoriously hampered by the reluctance of Au(I) towards oxidative addition. Here, the authors show that an hemilabile bidentate ligand promotes oxidative addition of aryl halides to Au(I) and the catalytic formation of biaryl coupling products.Abdallah ZeineddineLaura EstévezSonia Mallet-LadeiraKarinne MiqueuAbderrahmane AmgouneDidier BourissouNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Abdallah Zeineddine
Laura Estévez
Sonia Mallet-Ladeira
Karinne Miqueu
Abderrahmane Amgoune
Didier Bourissou
Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides
description Catalysis involving Au(I)/Au(III) cycles are notoriously hampered by the reluctance of Au(I) towards oxidative addition. Here, the authors show that an hemilabile bidentate ligand promotes oxidative addition of aryl halides to Au(I) and the catalytic formation of biaryl coupling products.
format article
author Abdallah Zeineddine
Laura Estévez
Sonia Mallet-Ladeira
Karinne Miqueu
Abderrahmane Amgoune
Didier Bourissou
author_facet Abdallah Zeineddine
Laura Estévez
Sonia Mallet-Ladeira
Karinne Miqueu
Abderrahmane Amgoune
Didier Bourissou
author_sort Abdallah Zeineddine
title Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides
title_short Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides
title_full Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides
title_fullStr Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides
title_full_unstemmed Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides
title_sort rational development of catalytic au(i)/au(iii) arylation involving mild oxidative addition of aryl halides
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/9659d77298bc497e9ccba56e9cd11a8d
work_keys_str_mv AT abdallahzeineddine rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides
AT lauraestevez rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides
AT soniamalletladeira rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides
AT karinnemiqueu rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides
AT abderrahmaneamgoune rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides
AT didierbourissou rationaldevelopmentofcatalyticauiauiiiarylationinvolvingmildoxidativeadditionofarylhalides
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