The halogen bond with isocyano carbon reduces isocyanide odor

Carbon atoms of various species typically function as acceptors of noncovalent interactions when they are part of a π-system. Here, the authors report their discovery of a noncovalent halogen bond involving the isocyano carbon lone pair, which results in adducts with strongly reduced isocyanide odor...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Alexander S. Mikherdov, Alexander S. Novikov, Vadim P. Boyarskiy, Vadim Yu. Kukushkin
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
Materias:
Q
Acceso en línea:https://doaj.org/article/965e0044297a4e3d98fcb31fa15b7721
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:965e0044297a4e3d98fcb31fa15b7721
record_format dspace
spelling oai:doaj.org-article:965e0044297a4e3d98fcb31fa15b77212021-12-02T17:38:25ZThe halogen bond with isocyano carbon reduces isocyanide odor10.1038/s41467-020-16748-x2041-1723https://doaj.org/article/965e0044297a4e3d98fcb31fa15b77212020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16748-xhttps://doaj.org/toc/2041-1723Carbon atoms of various species typically function as acceptors of noncovalent interactions when they are part of a π-system. Here, the authors report their discovery of a noncovalent halogen bond involving the isocyano carbon lone pair, which results in adducts with strongly reduced isocyanide odor.Alexander S. MikherdovAlexander S. NovikovVadim P. BoyarskiyVadim Yu. KukushkinNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Alexander S. Mikherdov
Alexander S. Novikov
Vadim P. Boyarskiy
Vadim Yu. Kukushkin
The halogen bond with isocyano carbon reduces isocyanide odor
description Carbon atoms of various species typically function as acceptors of noncovalent interactions when they are part of a π-system. Here, the authors report their discovery of a noncovalent halogen bond involving the isocyano carbon lone pair, which results in adducts with strongly reduced isocyanide odor.
format article
author Alexander S. Mikherdov
Alexander S. Novikov
Vadim P. Boyarskiy
Vadim Yu. Kukushkin
author_facet Alexander S. Mikherdov
Alexander S. Novikov
Vadim P. Boyarskiy
Vadim Yu. Kukushkin
author_sort Alexander S. Mikherdov
title The halogen bond with isocyano carbon reduces isocyanide odor
title_short The halogen bond with isocyano carbon reduces isocyanide odor
title_full The halogen bond with isocyano carbon reduces isocyanide odor
title_fullStr The halogen bond with isocyano carbon reduces isocyanide odor
title_full_unstemmed The halogen bond with isocyano carbon reduces isocyanide odor
title_sort halogen bond with isocyano carbon reduces isocyanide odor
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/965e0044297a4e3d98fcb31fa15b7721
work_keys_str_mv AT alexandersmikherdov thehalogenbondwithisocyanocarbonreducesisocyanideodor
AT alexandersnovikov thehalogenbondwithisocyanocarbonreducesisocyanideodor
AT vadimpboyarskiy thehalogenbondwithisocyanocarbonreducesisocyanideodor
AT vadimyukukushkin thehalogenbondwithisocyanocarbonreducesisocyanideodor
AT alexandersmikherdov halogenbondwithisocyanocarbonreducesisocyanideodor
AT alexandersnovikov halogenbondwithisocyanocarbonreducesisocyanideodor
AT vadimpboyarskiy halogenbondwithisocyanocarbonreducesisocyanideodor
AT vadimyukukushkin halogenbondwithisocyanocarbonreducesisocyanideodor
_version_ 1718379836909551616