The halogen bond with isocyano carbon reduces isocyanide odor

Carbon atoms of various species typically function as acceptors of noncovalent interactions when they are part of a π-system. Here, the authors report their discovery of a noncovalent halogen bond involving the isocyano carbon lone pair, which results in adducts with strongly reduced isocyanide odor...

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Autores principales: Alexander S. Mikherdov, Alexander S. Novikov, Vadim P. Boyarskiy, Vadim Yu. Kukushkin
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/965e0044297a4e3d98fcb31fa15b7721
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