Structural and rheological analysis of nickel enriched peraluminous glasses

This study describes the role of nickel oxide (NiO) in peraluminous glass. Peraluminous glass is defined by an excess of aluminium ions (Al3+) compared to modifier elements such as Na+, Li+ or Ca2+ ions. The study investigates the effect NiO incorporation on peraluminous glass homogeneity and proces...

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Autores principales: E. Hansen, D. Perret, I. Bardez-Giboire, S. Mure, C. Rapin
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Lenguaje:EN
Publicado: Elsevier 2021
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Acceso en línea:https://doaj.org/article/980af2df9f2d4cccb403f047e223da52
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spelling oai:doaj.org-article:980af2df9f2d4cccb403f047e223da522021-11-12T04:46:57ZStructural and rheological analysis of nickel enriched peraluminous glasses2590-159110.1016/j.nocx.2021.100069https://doaj.org/article/980af2df9f2d4cccb403f047e223da522021-09-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2590159121000108https://doaj.org/toc/2590-1591This study describes the role of nickel oxide (NiO) in peraluminous glass. Peraluminous glass is defined by an excess of aluminium ions (Al3+) compared to modifier elements such as Na+, Li+ or Ca2+ ions. The study investigates the effect NiO incorporation on peraluminous glass homogeneity and process ability. Quenched NiO-containing glass showed an incorporation limit greater than 12 wt% NiO (13.8 mol%), while slowly cooled glass showed a limit of 5 wt% NiO (5.8 mol%). Nickel oxide is also found to have a fludifying effect on peraluminous glasses. When the nickel oxide content is above its incorporation limit, the resulting crystals were found to have a significant effect on glass rheological properties. Finally, hypotheses are proposed as to the structural role of Ni in peraluminous glass based on the experimental results obtained.E. HansenD. PerretI. Bardez-GiboireS. MureC. RapinElsevierarticlePeraluminous glassIncorporation limitCrystallizationViscosityNickel oxideMaterials of engineering and construction. Mechanics of materialsTA401-492ChemistryQD1-999ENJournal of Non-Crystalline Solids: X, Vol 11, Iss , Pp 100069- (2021)
institution DOAJ
collection DOAJ
language EN
topic Peraluminous glass
Incorporation limit
Crystallization
Viscosity
Nickel oxide
Materials of engineering and construction. Mechanics of materials
TA401-492
Chemistry
QD1-999
spellingShingle Peraluminous glass
Incorporation limit
Crystallization
Viscosity
Nickel oxide
Materials of engineering and construction. Mechanics of materials
TA401-492
Chemistry
QD1-999
E. Hansen
D. Perret
I. Bardez-Giboire
S. Mure
C. Rapin
Structural and rheological analysis of nickel enriched peraluminous glasses
description This study describes the role of nickel oxide (NiO) in peraluminous glass. Peraluminous glass is defined by an excess of aluminium ions (Al3+) compared to modifier elements such as Na+, Li+ or Ca2+ ions. The study investigates the effect NiO incorporation on peraluminous glass homogeneity and process ability. Quenched NiO-containing glass showed an incorporation limit greater than 12 wt% NiO (13.8 mol%), while slowly cooled glass showed a limit of 5 wt% NiO (5.8 mol%). Nickel oxide is also found to have a fludifying effect on peraluminous glasses. When the nickel oxide content is above its incorporation limit, the resulting crystals were found to have a significant effect on glass rheological properties. Finally, hypotheses are proposed as to the structural role of Ni in peraluminous glass based on the experimental results obtained.
format article
author E. Hansen
D. Perret
I. Bardez-Giboire
S. Mure
C. Rapin
author_facet E. Hansen
D. Perret
I. Bardez-Giboire
S. Mure
C. Rapin
author_sort E. Hansen
title Structural and rheological analysis of nickel enriched peraluminous glasses
title_short Structural and rheological analysis of nickel enriched peraluminous glasses
title_full Structural and rheological analysis of nickel enriched peraluminous glasses
title_fullStr Structural and rheological analysis of nickel enriched peraluminous glasses
title_full_unstemmed Structural and rheological analysis of nickel enriched peraluminous glasses
title_sort structural and rheological analysis of nickel enriched peraluminous glasses
publisher Elsevier
publishDate 2021
url https://doaj.org/article/980af2df9f2d4cccb403f047e223da52
work_keys_str_mv AT ehansen structuralandrheologicalanalysisofnickelenrichedperaluminousglasses
AT dperret structuralandrheologicalanalysisofnickelenrichedperaluminousglasses
AT ibardezgiboire structuralandrheologicalanalysisofnickelenrichedperaluminousglasses
AT smure structuralandrheologicalanalysisofnickelenrichedperaluminousglasses
AT crapin structuralandrheologicalanalysisofnickelenrichedperaluminousglasses
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