Structural and rheological analysis of nickel enriched peraluminous glasses
This study describes the role of nickel oxide (NiO) in peraluminous glass. Peraluminous glass is defined by an excess of aluminium ions (Al3+) compared to modifier elements such as Na+, Li+ or Ca2+ ions. The study investigates the effect NiO incorporation on peraluminous glass homogeneity and proces...
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2021
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oai:doaj.org-article:980af2df9f2d4cccb403f047e223da522021-11-12T04:46:57ZStructural and rheological analysis of nickel enriched peraluminous glasses2590-159110.1016/j.nocx.2021.100069https://doaj.org/article/980af2df9f2d4cccb403f047e223da522021-09-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2590159121000108https://doaj.org/toc/2590-1591This study describes the role of nickel oxide (NiO) in peraluminous glass. Peraluminous glass is defined by an excess of aluminium ions (Al3+) compared to modifier elements such as Na+, Li+ or Ca2+ ions. The study investigates the effect NiO incorporation on peraluminous glass homogeneity and process ability. Quenched NiO-containing glass showed an incorporation limit greater than 12 wt% NiO (13.8 mol%), while slowly cooled glass showed a limit of 5 wt% NiO (5.8 mol%). Nickel oxide is also found to have a fludifying effect on peraluminous glasses. When the nickel oxide content is above its incorporation limit, the resulting crystals were found to have a significant effect on glass rheological properties. Finally, hypotheses are proposed as to the structural role of Ni in peraluminous glass based on the experimental results obtained.E. HansenD. PerretI. Bardez-GiboireS. MureC. RapinElsevierarticlePeraluminous glassIncorporation limitCrystallizationViscosityNickel oxideMaterials of engineering and construction. Mechanics of materialsTA401-492ChemistryQD1-999ENJournal of Non-Crystalline Solids: X, Vol 11, Iss , Pp 100069- (2021) |
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DOAJ |
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Peraluminous glass Incorporation limit Crystallization Viscosity Nickel oxide Materials of engineering and construction. Mechanics of materials TA401-492 Chemistry QD1-999 |
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Peraluminous glass Incorporation limit Crystallization Viscosity Nickel oxide Materials of engineering and construction. Mechanics of materials TA401-492 Chemistry QD1-999 E. Hansen D. Perret I. Bardez-Giboire S. Mure C. Rapin Structural and rheological analysis of nickel enriched peraluminous glasses |
description |
This study describes the role of nickel oxide (NiO) in peraluminous glass. Peraluminous glass is defined by an excess of aluminium ions (Al3+) compared to modifier elements such as Na+, Li+ or Ca2+ ions. The study investigates the effect NiO incorporation on peraluminous glass homogeneity and process ability. Quenched NiO-containing glass showed an incorporation limit greater than 12 wt% NiO (13.8 mol%), while slowly cooled glass showed a limit of 5 wt% NiO (5.8 mol%). Nickel oxide is also found to have a fludifying effect on peraluminous glasses. When the nickel oxide content is above its incorporation limit, the resulting crystals were found to have a significant effect on glass rheological properties. Finally, hypotheses are proposed as to the structural role of Ni in peraluminous glass based on the experimental results obtained. |
format |
article |
author |
E. Hansen D. Perret I. Bardez-Giboire S. Mure C. Rapin |
author_facet |
E. Hansen D. Perret I. Bardez-Giboire S. Mure C. Rapin |
author_sort |
E. Hansen |
title |
Structural and rheological analysis of nickel enriched peraluminous glasses |
title_short |
Structural and rheological analysis of nickel enriched peraluminous glasses |
title_full |
Structural and rheological analysis of nickel enriched peraluminous glasses |
title_fullStr |
Structural and rheological analysis of nickel enriched peraluminous glasses |
title_full_unstemmed |
Structural and rheological analysis of nickel enriched peraluminous glasses |
title_sort |
structural and rheological analysis of nickel enriched peraluminous glasses |
publisher |
Elsevier |
publishDate |
2021 |
url |
https://doaj.org/article/980af2df9f2d4cccb403f047e223da52 |
work_keys_str_mv |
AT ehansen structuralandrheologicalanalysisofnickelenrichedperaluminousglasses AT dperret structuralandrheologicalanalysisofnickelenrichedperaluminousglasses AT ibardezgiboire structuralandrheologicalanalysisofnickelenrichedperaluminousglasses AT smure structuralandrheologicalanalysisofnickelenrichedperaluminousglasses AT crapin structuralandrheologicalanalysisofnickelenrichedperaluminousglasses |
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