Site-selective electrooxidation of methylarenes to aromatic acetals

Site-selective electrooxidation of methylarenes to aromatic acetals

Benzylic oxygenation of methylarenes is a direct but challenging method for aldehyde synthesis from simple starting materials. Here, the authors show an electrochemical, site-selective method for the oxidation of methyl benzoheterocycles to aromatic acetals without using chemical oxidants or transit...

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Autores principales: Peng Xiong, Huai-Bo Zhao, Xue-Ting Fan, Liang-Hua Jie, Hao Long, Pin Xu, Zhan-Jiang Liu, Zheng-Jian Wu, Jun Cheng, Hai-Chao Xu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/9879b00c89c44d29b40cc1f9ba7d8744
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spelling oai:doaj.org-article:9879b00c89c44d29b40cc1f9ba7d87442021-12-02T18:24:49ZSite-selective electrooxidation of methylarenes to aromatic acetals10.1038/s41467-020-16519-82041-1723https://doaj.org/article/9879b00c89c44d29b40cc1f9ba7d87442020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16519-8https://doaj.org/toc/2041-1723Benzylic oxygenation of methylarenes is a direct but challenging method for aldehyde synthesis from simple starting materials. Here, the authors show an electrochemical, site-selective method for the oxidation of methyl benzoheterocycles to aromatic acetals without using chemical oxidants or transition metal catalysts.Peng XiongHuai-Bo ZhaoXue-Ting FanLiang-Hua JieHao LongPin XuZhan-Jiang LiuZheng-Jian WuJun ChengHai-Chao XuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Peng Xiong
Huai-Bo Zhao
Xue-Ting Fan
Liang-Hua Jie
Hao Long
Pin Xu
Zhan-Jiang Liu
Zheng-Jian Wu
Jun Cheng
Hai-Chao Xu
Site-selective electrooxidation of methylarenes to aromatic acetals
description Benzylic oxygenation of methylarenes is a direct but challenging method for aldehyde synthesis from simple starting materials. Here, the authors show an electrochemical, site-selective method for the oxidation of methyl benzoheterocycles to aromatic acetals without using chemical oxidants or transition metal catalysts.
format article
author Peng Xiong
Huai-Bo Zhao
Xue-Ting Fan
Liang-Hua Jie
Hao Long
Pin Xu
Zhan-Jiang Liu
Zheng-Jian Wu
Jun Cheng
Hai-Chao Xu
author_facet Peng Xiong
Huai-Bo Zhao
Xue-Ting Fan
Liang-Hua Jie
Hao Long
Pin Xu
Zhan-Jiang Liu
Zheng-Jian Wu
Jun Cheng
Hai-Chao Xu
author_sort Peng Xiong
title Site-selective electrooxidation of methylarenes to aromatic acetals
title_short Site-selective electrooxidation of methylarenes to aromatic acetals
title_full Site-selective electrooxidation of methylarenes to aromatic acetals
title_fullStr Site-selective electrooxidation of methylarenes to aromatic acetals
title_full_unstemmed Site-selective electrooxidation of methylarenes to aromatic acetals
title_sort site-selective electrooxidation of methylarenes to aromatic acetals
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/9879b00c89c44d29b40cc1f9ba7d8744
work_keys_str_mv AT pengxiong siteselectiveelectrooxidationofmethylarenestoaromaticacetals
AT huaibozhao siteselectiveelectrooxidationofmethylarenestoaromaticacetals
AT xuetingfan siteselectiveelectrooxidationofmethylarenestoaromaticacetals
AT lianghuajie siteselectiveelectrooxidationofmethylarenestoaromaticacetals
AT haolong siteselectiveelectrooxidationofmethylarenestoaromaticacetals
AT pinxu siteselectiveelectrooxidationofmethylarenestoaromaticacetals
AT zhanjiangliu siteselectiveelectrooxidationofmethylarenestoaromaticacetals
AT zhengjianwu siteselectiveelectrooxidationofmethylarenestoaromaticacetals
AT juncheng siteselectiveelectrooxidationofmethylarenestoaromaticacetals
AT haichaoxu siteselectiveelectrooxidationofmethylarenestoaromaticacetals
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