Ambient methane functionalization initiated by electrochemical oxidation of a vanadium (V)-oxo dimer

The undesirable geological release of methane at remote locations can be lessened through an efficient methane conversion process. Here, the authors report selective ambient functionalization of methane by a vanadium (V)-oxo electrocatalyst with a low activation energy and a high turnover frequency.

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Autores principales: Jiao Deng, Sheng-Chih Lin, Jack Fuller, Jesus A. Iñiguez, Danlei Xiang, Di Yang, Gary Chan, Hao Ming Chen, Anastassia N. Alexandrova, Chong Liu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/9906f58da3e1440997cb02f9bb2326bf
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Sumario:The undesirable geological release of methane at remote locations can be lessened through an efficient methane conversion process. Here, the authors report selective ambient functionalization of methane by a vanadium (V)-oxo electrocatalyst with a low activation energy and a high turnover frequency.