Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
Functionalization of the multiple, similar, boron-hydrogen bonds in carboranes is difficult to achieve with selectivity. Here the authors report an iridium-catalysed borylation ofo-carboranes with high yields and regioselectivities.
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Main Authors: | , , |
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Format: | article |
Language: | EN |
Published: |
Nature Portfolio
2017
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Subjects: | |
Online Access: | https://doaj.org/article/990b953c1ff34d999e30291cf61a0dc1 |
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Summary: | Functionalization of the multiple, similar, boron-hydrogen bonds in carboranes is difficult to achieve with selectivity. Here the authors report an iridium-catalysed borylation ofo-carboranes with high yields and regioselectivities. |
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