Iridium-catalysed regioselective borylation of carboranes via direct B–H activation

Functionalization of the multiple, similar, boron-hydrogen bonds in carboranes is difficult to achieve with selectivity. Here the authors report an iridium-catalysed borylation ofo-carboranes with high yields and regioselectivities.

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Autores principales:	Ruofei Cheng, Zaozao Qiu, Zuowei Xie
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/990b953c1ff34d999e30291cf61a0dc1
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spelling	oai:doaj.org-article:990b953c1ff34d999e30291cf61a0dc12021-12-02T15:38:41ZIridium-catalysed regioselective borylation of carboranes via direct B–H activation10.1038/ncomms148272041-1723https://doaj.org/article/990b953c1ff34d999e30291cf61a0dc12017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14827https://doaj.org/toc/2041-1723Functionalization of the multiple, similar, boron-hydrogen bonds in carboranes is difficult to achieve with selectivity. Here the authors report an iridium-catalysed borylation ofo-carboranes with high yields and regioselectivities.Ruofei ChengZaozao QiuZuowei XieNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Ruofei Cheng Zaozao Qiu Zuowei Xie Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
description	Functionalization of the multiple, similar, boron-hydrogen bonds in carboranes is difficult to achieve with selectivity. Here the authors report an iridium-catalysed borylation ofo-carboranes with high yields and regioselectivities.
format	article
author	Ruofei Cheng Zaozao Qiu Zuowei Xie
author_facet	Ruofei Cheng Zaozao Qiu Zuowei Xie
author_sort	Ruofei Cheng
title	Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
title_short	Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
title_full	Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
title_fullStr	Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
title_full_unstemmed	Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
title_sort	iridium-catalysed regioselective borylation of carboranes via direct b–h activation
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/990b953c1ff34d999e30291cf61a0dc1
work_keys_str_mv	AT ruofeicheng iridiumcatalysedregioselectiveborylationofcarboranesviadirectbhactivation AT zaozaoqiu iridiumcatalysedregioselectiveborylationofcarboranesviadirectbhactivation AT zuoweixie iridiumcatalysedregioselectiveborylationofcarboranesviadirectbhactivation
_version_	1718386128600432640

Iridium-catalysed regioselective borylation of carboranes via direct B–H activation

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