Nanoclay assisted ultra-drawing of polypropylene tapes
Isotactic polypropylene (i-PP) – montmorillonite (MMT) nanocomposite films were prepared by melt-compounding and hot-pressing. The influence of organoclays on the mechanical properties and drawability of these isotropic composite films was investigated. Ultimate properties of solid-state drawn PP ta...
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Taylor & Francis Group
2019
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oai:doaj.org-article:99ef064e11644c77a2865623914eda3a2021-12-02T09:11:10ZNanoclay assisted ultra-drawing of polypropylene tapes2055-033210.1080/20550324.2019.1671038https://doaj.org/article/99ef064e11644c77a2865623914eda3a2019-10-01T00:00:00Zhttp://dx.doi.org/10.1080/20550324.2019.1671038https://doaj.org/toc/2055-0332Isotactic polypropylene (i-PP) – montmorillonite (MMT) nanocomposite films were prepared by melt-compounding and hot-pressing. The influence of organoclays on the mechanical properties and drawability of these isotropic composite films was investigated. Ultimate properties of solid-state drawn PP tapes incorporating 2.5 wt% MMT outperformed those of pure PP tapes. Interestingly, these improvements were found not to be the result of a mechanical reinforcement effect of the nanoclay platelets but merely the result of a more efficient ultra-drawing mechanism with MMT acting as a processing additive that altered initial polymer morphology and drawing behaviour. Hence, the introduction of MMT resulted in higher ultimate draw ratios and subsequently higher ultimate mechanical properties of the oriented nanocomposite tapes.Tim B. van ErpChristopher T. ReynoldsEmiliano BilottiTon PeijsTaylor & Francis Grouparticlepolypropyleneclaydrawingorientationfibremechanical propertiesMaterials of engineering and construction. Mechanics of materialsTA401-492Polymers and polymer manufactureTP1080-1185ENNanocomposites, Vol 5, Iss 4, Pp 114-123 (2019) |
institution |
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DOAJ |
language |
EN |
topic |
polypropylene clay drawing orientation fibre mechanical properties Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185 |
spellingShingle |
polypropylene clay drawing orientation fibre mechanical properties Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185 Tim B. van Erp Christopher T. Reynolds Emiliano Bilotti Ton Peijs Nanoclay assisted ultra-drawing of polypropylene tapes |
description |
Isotactic polypropylene (i-PP) – montmorillonite (MMT) nanocomposite films were prepared by melt-compounding and hot-pressing. The influence of organoclays on the mechanical properties and drawability of these isotropic composite films was investigated. Ultimate properties of solid-state drawn PP tapes incorporating 2.5 wt% MMT outperformed those of pure PP tapes. Interestingly, these improvements were found not to be the result of a mechanical reinforcement effect of the nanoclay platelets but merely the result of a more efficient ultra-drawing mechanism with MMT acting as a processing additive that altered initial polymer morphology and drawing behaviour. Hence, the introduction of MMT resulted in higher ultimate draw ratios and subsequently higher ultimate mechanical properties of the oriented nanocomposite tapes. |
format |
article |
author |
Tim B. van Erp Christopher T. Reynolds Emiliano Bilotti Ton Peijs |
author_facet |
Tim B. van Erp Christopher T. Reynolds Emiliano Bilotti Ton Peijs |
author_sort |
Tim B. van Erp |
title |
Nanoclay assisted ultra-drawing of polypropylene tapes |
title_short |
Nanoclay assisted ultra-drawing of polypropylene tapes |
title_full |
Nanoclay assisted ultra-drawing of polypropylene tapes |
title_fullStr |
Nanoclay assisted ultra-drawing of polypropylene tapes |
title_full_unstemmed |
Nanoclay assisted ultra-drawing of polypropylene tapes |
title_sort |
nanoclay assisted ultra-drawing of polypropylene tapes |
publisher |
Taylor & Francis Group |
publishDate |
2019 |
url |
https://doaj.org/article/99ef064e11644c77a2865623914eda3a |
work_keys_str_mv |
AT timbvanerp nanoclayassistedultradrawingofpolypropylenetapes AT christophertreynolds nanoclayassistedultradrawingofpolypropylenetapes AT emilianobilotti nanoclayassistedultradrawingofpolypropylenetapes AT tonpeijs nanoclayassistedultradrawingofpolypropylenetapes |
_version_ |
1718398199974068224 |