Ultralight, Ultraflexible, Anisotropic, Highly Thermally Conductive Graphene Aerogel Films
Graphene aerogels have attracted much attention as a promising material for various applications. The unusually high intrinsic thermal conductivity of individual graphene sheets makes an obvious contrast with the thermal insulating performance of assembled 3D graphene materials. We report the prepar...
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2021
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oai:doaj.org-article:9a8b0f883f3e43718a11c9eea789d0902021-11-25T18:27:57ZUltralight, Ultraflexible, Anisotropic, Highly Thermally Conductive Graphene Aerogel Films10.3390/molecules262268671420-3049https://doaj.org/article/9a8b0f883f3e43718a11c9eea789d0902021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/6867https://doaj.org/toc/1420-3049Graphene aerogels have attracted much attention as a promising material for various applications. The unusually high intrinsic thermal conductivity of individual graphene sheets makes an obvious contrast with the thermal insulating performance of assembled 3D graphene materials. We report the preparation of anisotropy 3D graphene aerogel films (GAFs) made from tightly packed graphene films using a thermal expansion method. GAFs with different thicknesses and an ultimate low density of 4.19 mg cm<sup>−3</sup> were obtained. GAFs show high anisotropy on average cross-plane thermal conductivity (K<sub>⊥</sub>) and average in-plane thermal conductivity (K<sub>||</sub>). Additionally, uniaxially compressed GAFs performed a large elongation of 11.76% due to the Z-shape folding of graphene layers. Our results reveal the ultralight, ultraflexible, highly thermally conductive, anisotropy GAFs, as well as the fundamental evolution of macroscopic assembled graphene materials at elevated temperature.Zheng LiuQinsheng WangLinlin HouYingjun LiuZheng LiMDPI AGarticlegraphene aerogel filmanisotropic materialthermal conductivityOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6867, p 6867 (2021) |
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graphene aerogel film anisotropic material thermal conductivity Organic chemistry QD241-441 |
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graphene aerogel film anisotropic material thermal conductivity Organic chemistry QD241-441 Zheng Liu Qinsheng Wang Linlin Hou Yingjun Liu Zheng Li Ultralight, Ultraflexible, Anisotropic, Highly Thermally Conductive Graphene Aerogel Films |
description |
Graphene aerogels have attracted much attention as a promising material for various applications. The unusually high intrinsic thermal conductivity of individual graphene sheets makes an obvious contrast with the thermal insulating performance of assembled 3D graphene materials. We report the preparation of anisotropy 3D graphene aerogel films (GAFs) made from tightly packed graphene films using a thermal expansion method. GAFs with different thicknesses and an ultimate low density of 4.19 mg cm<sup>−3</sup> were obtained. GAFs show high anisotropy on average cross-plane thermal conductivity (K<sub>⊥</sub>) and average in-plane thermal conductivity (K<sub>||</sub>). Additionally, uniaxially compressed GAFs performed a large elongation of 11.76% due to the Z-shape folding of graphene layers. Our results reveal the ultralight, ultraflexible, highly thermally conductive, anisotropy GAFs, as well as the fundamental evolution of macroscopic assembled graphene materials at elevated temperature. |
format |
article |
author |
Zheng Liu Qinsheng Wang Linlin Hou Yingjun Liu Zheng Li |
author_facet |
Zheng Liu Qinsheng Wang Linlin Hou Yingjun Liu Zheng Li |
author_sort |
Zheng Liu |
title |
Ultralight, Ultraflexible, Anisotropic, Highly Thermally Conductive Graphene Aerogel Films |
title_short |
Ultralight, Ultraflexible, Anisotropic, Highly Thermally Conductive Graphene Aerogel Films |
title_full |
Ultralight, Ultraflexible, Anisotropic, Highly Thermally Conductive Graphene Aerogel Films |
title_fullStr |
Ultralight, Ultraflexible, Anisotropic, Highly Thermally Conductive Graphene Aerogel Films |
title_full_unstemmed |
Ultralight, Ultraflexible, Anisotropic, Highly Thermally Conductive Graphene Aerogel Films |
title_sort |
ultralight, ultraflexible, anisotropic, highly thermally conductive graphene aerogel films |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/9a8b0f883f3e43718a11c9eea789d090 |
work_keys_str_mv |
AT zhengliu ultralightultraflexibleanisotropichighlythermallyconductivegrapheneaerogelfilms AT qinshengwang ultralightultraflexibleanisotropichighlythermallyconductivegrapheneaerogelfilms AT linlinhou ultralightultraflexibleanisotropichighlythermallyconductivegrapheneaerogelfilms AT yingjunliu ultralightultraflexibleanisotropichighlythermallyconductivegrapheneaerogelfilms AT zhengli ultralightultraflexibleanisotropichighlythermallyconductivegrapheneaerogelfilms |
_version_ |
1718411147579752448 |