A low-cost, low-density, and corrosion resistant AlFeMnSi compositionally complex alloy

Abstract A compositionally complex alloy was designed, consisting of equiatomic concentrations of four low-cost commodity elements (Al, Fe, Mn, and Si). The alloy was characterized using scanning electron microscopy and energy-dispersive X-ray spectroscopy. The corrosion of the AlFeMnSi alloy, as ev...

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Bibliographic Details
Main Authors: S. P. O’Brien, J. Christudasjustus, L. Esteves, S. Vijayan, J. R. Jinschek, N. Birbilis, R. K. Gupta
Format: article
Language:EN
Published: Nature Portfolio 2021
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Online Access:https://doaj.org/article/9b7e263a24dc4acc8a17c44c4d22b1e4
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Summary:Abstract A compositionally complex alloy was designed, consisting of equiatomic concentrations of four low-cost commodity elements (Al, Fe, Mn, and Si). The alloy was characterized using scanning electron microscopy and energy-dispersive X-ray spectroscopy. The corrosion of the AlFeMnSi alloy, as evaluated using potentiodynamic polarization tests and electrochemical impedance spectroscopy in 0.6 M NaCl solution, was comparable with that of stainless steel (SS) 304L. Detailed X-ray photoelectron spectroscopy analysis was carried out, including the determination of high-resolution spectra and surface sputtering. In addition, scanning transmission electron microscopy was also used to study the surface film(s) developed after constant immersion. The AlFeMnSi alloy exhibited a unique form of ‘passivity’ that arises from the development of a silicon-rich surface film from dynamic incongruent dissolution.