Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2

Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2

Compounds bearing a carbonyl group, such as aldehydes and ketones, are important industrial chemicals and widespread in pharmaceuticals and natural products. Here, the authors report a strategy for visible-light photoredox-catalyzed umpolung carboxylation of diverse carbonyl compounds with CO2, to g...

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Autores principales: Guang-Mei Cao, Xin-Long Hu, Li-Li Liao, Si-Shun Yan, Lei Song, Jason J. Chruma, Li Gong, Da-Gang Yu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/9b7f948cac0f47a2b8b39d2e4feae65e
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spelling oai:doaj.org-article:9b7f948cac0f47a2b8b39d2e4feae65e2021-12-02T15:57:09ZVisible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO210.1038/s41467-021-23447-82041-1723https://doaj.org/article/9b7f948cac0f47a2b8b39d2e4feae65e2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23447-8https://doaj.org/toc/2041-1723Compounds bearing a carbonyl group, such as aldehydes and ketones, are important industrial chemicals and widespread in pharmaceuticals and natural products. Here, the authors report a strategy for visible-light photoredox-catalyzed umpolung carboxylation of diverse carbonyl compounds with CO2, to generate valuable α-hydroxycarboxylic acids.Guang-Mei CaoXin-Long HuLi-Li LiaoSi-Shun YanLei SongJason J. ChrumaLi GongDa-Gang YuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Guang-Mei Cao
Xin-Long Hu
Li-Li Liao
Si-Shun Yan
Lei Song
Jason J. Chruma
Li Gong
Da-Gang Yu
Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2
description Compounds bearing a carbonyl group, such as aldehydes and ketones, are important industrial chemicals and widespread in pharmaceuticals and natural products. Here, the authors report a strategy for visible-light photoredox-catalyzed umpolung carboxylation of diverse carbonyl compounds with CO2, to generate valuable α-hydroxycarboxylic acids.
format article
author Guang-Mei Cao
Xin-Long Hu
Li-Li Liao
Si-Shun Yan
Lei Song
Jason J. Chruma
Li Gong
Da-Gang Yu
author_facet Guang-Mei Cao
Xin-Long Hu
Li-Li Liao
Si-Shun Yan
Lei Song
Jason J. Chruma
Li Gong
Da-Gang Yu
author_sort Guang-Mei Cao
title Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2
title_short Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2
title_full Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2
title_fullStr Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2
title_full_unstemmed Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2
title_sort visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with co2
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/9b7f948cac0f47a2b8b39d2e4feae65e
work_keys_str_mv AT guangmeicao visiblelightphotoredoxcatalyzedumpolungcarboxylationofcarbonylcompoundswithco2
AT xinlonghu visiblelightphotoredoxcatalyzedumpolungcarboxylationofcarbonylcompoundswithco2
AT lililiao visiblelightphotoredoxcatalyzedumpolungcarboxylationofcarbonylcompoundswithco2
AT sishunyan visiblelightphotoredoxcatalyzedumpolungcarboxylationofcarbonylcompoundswithco2
AT leisong visiblelightphotoredoxcatalyzedumpolungcarboxylationofcarbonylcompoundswithco2
AT jasonjchruma visiblelightphotoredoxcatalyzedumpolungcarboxylationofcarbonylcompoundswithco2
AT ligong visiblelightphotoredoxcatalyzedumpolungcarboxylationofcarbonylcompoundswithco2
AT dagangyu visiblelightphotoredoxcatalyzedumpolungcarboxylationofcarbonylcompoundswithco2
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