Revealing electronic state-switching at conical intersections in alkyl iodides by ultrafast XUV transient absorption spectroscopy

The reaction trajectories of photoexcited molecules may involve transitions through conical intersections, which are ubiquitous in nature but challenging to characterize. Here the authors provide a complete mapping of molecular dissociation of two model alkyl halides by ultrafast XUV transient absor...

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Autores principales: Kristina F. Chang, Maurizio Reduzzi, Han Wang, Sonia M. Poullain, Yuki Kobayashi, Lou Barreau, David Prendergast, Daniel M. Neumark, Stephen R. Leone
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/9c266f5f9e174f2693696b865dbc3d20
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Sumario:The reaction trajectories of photoexcited molecules may involve transitions through conical intersections, which are ubiquitous in nature but challenging to characterize. Here the authors provide a complete mapping of molecular dissociation of two model alkyl halides by ultrafast XUV transient absorption.