Bimetallic Cu/Fe Catalysts for Ibuprofen Mineralization

At present, the use of conventional wastewater processes is becoming increasingly challenging, mainly due to the presence of biorecalcitrant organic matter. Advanced oxidation processes such as Fenton, Fenton-like and hybrid processes have been successfully employed for the treatment of highly conce...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Sajid Hussain, Eleonora Aneggi, Daniele Goi, Alessandro Trovarelli
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	Fenton-like oxidation heterogeneous reaction bimetallic catalyst ibuprofen wastewater treatment Chemical technology TP1-1185 Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/9c3130ba81c6494c831764f2adefad25
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:9c3130ba81c6494c831764f2adefad25
record_format	dspace
spelling	oai:doaj.org-article:9c3130ba81c6494c831764f2adefad252021-11-25T17:06:35ZBimetallic Cu/Fe Catalysts for Ibuprofen Mineralization10.3390/catal111113832073-4344https://doaj.org/article/9c3130ba81c6494c831764f2adefad252021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4344/11/11/1383https://doaj.org/toc/2073-4344At present, the use of conventional wastewater processes is becoming increasingly challenging, mainly due to the presence of biorecalcitrant organic matter. Advanced oxidation processes such as Fenton, Fenton-like and hybrid processes have been successfully employed for the treatment of highly concentrated and toxic non-biodegradable pollutants. Here, a series of bimetallic catalysts, based on Cu/Fe supported over ZrO<sub>2,</sub> were investigated for the mineralization of ibuprofen with a heterogeneous Fenton-like reaction. The materials were prepared by incipient wetness impregnation and characterized by standard techniques. Temperature-programmed experiments highlighted the promotion of the reduction in CuO due to the synergistic effects of the coupled redox cycles of copper (Cu<sup>2+</sup>/Cu<sup>+</sup>) and iron (Fe<sup>+3</sup>/Fe<sup>+2</sup>). 5%Cu-5%Fe/ZrO<sub>2</sub> not only displays the highest ibuprofen mineralization (83%) under optimum conditions but also exploits its activity in a wider range of pH (3–5) with extremely low metal leaching. The recycling of bimetallic catalysts reveals that only the 5%Cu-5%Fe/ZrO<sub>2</sub> system is able to provide sustainable activity in heterogeneous Fenton process.Sajid HussainEleonora AneggiDaniele GoiAlessandro TrovarelliMDPI AGarticleFenton-like oxidationheterogeneous reactionbimetallic catalystibuprofenwastewater treatmentChemical technologyTP1-1185ChemistryQD1-999ENCatalysts, Vol 11, Iss 1383, p 1383 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Fenton-like oxidation heterogeneous reaction bimetallic catalyst ibuprofen wastewater treatment Chemical technology TP1-1185 Chemistry QD1-999
spellingShingle	Fenton-like oxidation heterogeneous reaction bimetallic catalyst ibuprofen wastewater treatment Chemical technology TP1-1185 Chemistry QD1-999 Sajid Hussain Eleonora Aneggi Daniele Goi Alessandro Trovarelli Bimetallic Cu/Fe Catalysts for Ibuprofen Mineralization
description	At present, the use of conventional wastewater processes is becoming increasingly challenging, mainly due to the presence of biorecalcitrant organic matter. Advanced oxidation processes such as Fenton, Fenton-like and hybrid processes have been successfully employed for the treatment of highly concentrated and toxic non-biodegradable pollutants. Here, a series of bimetallic catalysts, based on Cu/Fe supported over ZrO<sub>2,</sub> were investigated for the mineralization of ibuprofen with a heterogeneous Fenton-like reaction. The materials were prepared by incipient wetness impregnation and characterized by standard techniques. Temperature-programmed experiments highlighted the promotion of the reduction in CuO due to the synergistic effects of the coupled redox cycles of copper (Cu<sup>2+</sup>/Cu<sup>+</sup>) and iron (Fe<sup>+3</sup>/Fe<sup>+2</sup>). 5%Cu-5%Fe/ZrO<sub>2</sub> not only displays the highest ibuprofen mineralization (83%) under optimum conditions but also exploits its activity in a wider range of pH (3–5) with extremely low metal leaching. The recycling of bimetallic catalysts reveals that only the 5%Cu-5%Fe/ZrO<sub>2</sub> system is able to provide sustainable activity in heterogeneous Fenton process.
format	article
author	Sajid Hussain Eleonora Aneggi Daniele Goi Alessandro Trovarelli
author_facet	Sajid Hussain Eleonora Aneggi Daniele Goi Alessandro Trovarelli
author_sort	Sajid Hussain
title	Bimetallic Cu/Fe Catalysts for Ibuprofen Mineralization
title_short	Bimetallic Cu/Fe Catalysts for Ibuprofen Mineralization
title_full	Bimetallic Cu/Fe Catalysts for Ibuprofen Mineralization
title_fullStr	Bimetallic Cu/Fe Catalysts for Ibuprofen Mineralization
title_full_unstemmed	Bimetallic Cu/Fe Catalysts for Ibuprofen Mineralization
title_sort	bimetallic cu/fe catalysts for ibuprofen mineralization
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/9c3130ba81c6494c831764f2adefad25
work_keys_str_mv	AT sajidhussain bimetalliccufecatalystsforibuprofenmineralization AT eleonoraaneggi bimetalliccufecatalystsforibuprofenmineralization AT danielegoi bimetalliccufecatalystsforibuprofenmineralization AT alessandrotrovarelli bimetalliccufecatalystsforibuprofenmineralization
_version_	1718412728313315328

Bimetallic Cu/Fe Catalysts for Ibuprofen Mineralization

Ejemplares similares