Highly Enhanced Electrocatalytic Performances with Dendritic Bimetallic Palladium-Based Nanocrystals

The exploration of efficient nanocatalysts with high activity and stability towards water electrolysis and fuel cell applications is extremely important for the advancement of electrochemical reactions. However, it remains challenging. Controlling the morphology of bimetallic Pd–Pt nanostructures ca...

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Autores principales:	Respati K. Pramadewandaru, Jeong-Hu Shim, Young Wook Lee, Jong Wook Hong
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	nanodendrites alloy nanocrystals Pd–Pt electrocatalysis hydrogen evolution reactions methanol oxidation reaction Chemical technology TP1-1185 Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/9c788269f23f42a28ca50f48a51a674c
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spelling	oai:doaj.org-article:9c788269f23f42a28ca50f48a51a674c2021-11-25T17:06:03ZHighly Enhanced Electrocatalytic Performances with Dendritic Bimetallic Palladium-Based Nanocrystals10.3390/catal111113372073-4344https://doaj.org/article/9c788269f23f42a28ca50f48a51a674c2021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4344/11/11/1337https://doaj.org/toc/2073-4344The exploration of efficient nanocatalysts with high activity and stability towards water electrolysis and fuel cell applications is extremely important for the advancement of electrochemical reactions. However, it remains challenging. Controlling the morphology of bimetallic Pd–Pt nanostructures can be a great way to improve their electrocatalytic properties compared with previously developed catalysts. Herein, we synthesize bimetallic Pd–Pt nanodendrites, which consist of a dense matrix of unsaturated coordination atoms and high porosity. The concentration of cetyltrimethylammonium chloride was significant for the morphology and size of the Pd–Pt nanodendrites. Pd–Pt nanodendrites prepared by cetyltrimethylammonium chloride (200 mM) showed higher activities towards both the hydrogen evolution reaction and methanol oxidation reaction compared to their different Pd–Pt nanodendrite counterparts, commercial Pd, and Pt catalysts, which was attributed to numerous unsaturated surface atoms in well-developed single branches.Respati K. PramadewandaruJeong-Hu ShimYoung Wook LeeJong Wook HongMDPI AGarticlenanodendritesalloy nanocrystalsPd–Ptelectrocatalysishydrogen evolution reactionsmethanol oxidation reactionChemical technologyTP1-1185ChemistryQD1-999ENCatalysts, Vol 11, Iss 1337, p 1337 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	nanodendrites alloy nanocrystals Pd–Pt electrocatalysis hydrogen evolution reactions methanol oxidation reaction Chemical technology TP1-1185 Chemistry QD1-999
spellingShingle	nanodendrites alloy nanocrystals Pd–Pt electrocatalysis hydrogen evolution reactions methanol oxidation reaction Chemical technology TP1-1185 Chemistry QD1-999 Respati K. Pramadewandaru Jeong-Hu Shim Young Wook Lee Jong Wook Hong Highly Enhanced Electrocatalytic Performances with Dendritic Bimetallic Palladium-Based Nanocrystals
description	The exploration of efficient nanocatalysts with high activity and stability towards water electrolysis and fuel cell applications is extremely important for the advancement of electrochemical reactions. However, it remains challenging. Controlling the morphology of bimetallic Pd–Pt nanostructures can be a great way to improve their electrocatalytic properties compared with previously developed catalysts. Herein, we synthesize bimetallic Pd–Pt nanodendrites, which consist of a dense matrix of unsaturated coordination atoms and high porosity. The concentration of cetyltrimethylammonium chloride was significant for the morphology and size of the Pd–Pt nanodendrites. Pd–Pt nanodendrites prepared by cetyltrimethylammonium chloride (200 mM) showed higher activities towards both the hydrogen evolution reaction and methanol oxidation reaction compared to their different Pd–Pt nanodendrite counterparts, commercial Pd, and Pt catalysts, which was attributed to numerous unsaturated surface atoms in well-developed single branches.
format	article
author	Respati K. Pramadewandaru Jeong-Hu Shim Young Wook Lee Jong Wook Hong
author_facet	Respati K. Pramadewandaru Jeong-Hu Shim Young Wook Lee Jong Wook Hong
author_sort	Respati K. Pramadewandaru
title	Highly Enhanced Electrocatalytic Performances with Dendritic Bimetallic Palladium-Based Nanocrystals
title_short	Highly Enhanced Electrocatalytic Performances with Dendritic Bimetallic Palladium-Based Nanocrystals
title_full	Highly Enhanced Electrocatalytic Performances with Dendritic Bimetallic Palladium-Based Nanocrystals
title_fullStr	Highly Enhanced Electrocatalytic Performances with Dendritic Bimetallic Palladium-Based Nanocrystals
title_full_unstemmed	Highly Enhanced Electrocatalytic Performances with Dendritic Bimetallic Palladium-Based Nanocrystals
title_sort	highly enhanced electrocatalytic performances with dendritic bimetallic palladium-based nanocrystals
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/9c788269f23f42a28ca50f48a51a674c
work_keys_str_mv	AT respatikpramadewandaru highlyenhancedelectrocatalyticperformanceswithdendriticbimetallicpalladiumbasednanocrystals AT jeonghushim highlyenhancedelectrocatalyticperformanceswithdendriticbimetallicpalladiumbasednanocrystals AT youngwooklee highlyenhancedelectrocatalyticperformanceswithdendriticbimetallicpalladiumbasednanocrystals AT jongwookhong highlyenhancedelectrocatalyticperformanceswithdendriticbimetallicpalladiumbasednanocrystals
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Highly Enhanced Electrocatalytic Performances with Dendritic Bimetallic Palladium-Based Nanocrystals

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