Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders
Photocatalytic nanomaterials, using only light as the source of excitation, have been developed for the breakdown of volatile organic compounds (VOCs) in air for a long time. It is a tough challenge to immobilize these powder photocatalysts and prevent their entrainment with the gas stream. Conventi...
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2021
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oai:doaj.org-article:9d35bf0d190a43cf81aa105f4e7e1cf92021-11-11T18:33:41ZDeposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders10.3390/molecules262165841420-3049https://doaj.org/article/9d35bf0d190a43cf81aa105f4e7e1cf92021-10-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/21/6584https://doaj.org/toc/1420-3049Photocatalytic nanomaterials, using only light as the source of excitation, have been developed for the breakdown of volatile organic compounds (VOCs) in air for a long time. It is a tough challenge to immobilize these powder photocatalysts and prevent their entrainment with the gas stream. Conventional methods for making stable films typically require expensive deposition equipment and only allow the deposition of very thin layers with limited photocatalytic performance. The present work presents an alternative approach, using the combination of commercially available photocatalytic nanopowders and a polymer or inorganic sol–gel-based matrix. Analysis of the photocatalytic degradation of ethanol was studied for these layers on metallic substrates, proving a difference in photocatalytic activity for different types of stable layers. The sol–gel-based <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>TiO</mi><mn>2</mn></msub></semantics></math></inline-formula> layers showed an improved photocatalytic activity of the nanomaterials compared with the polymer <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>TiO</mi><mn>2</mn></msub></semantics></math></inline-formula> layers. In addition, the used preparation methods require only a limited amount of photocatalyst, little equipment, and allow easy upscaling.Ewoud CosaertCédric WolfsStéphanie D. LambertGeraldine J. HeynderickxDirk PoelmanMDPI AGarticlephotocatalysisTiO<sub>2</sub>sol–gelPEGPMMAPVPOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6584, p 6584 (2021) |
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photocatalysis TiO<sub>2</sub> sol–gel PEG PMMA PVP Organic chemistry QD241-441 |
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photocatalysis TiO<sub>2</sub> sol–gel PEG PMMA PVP Organic chemistry QD241-441 Ewoud Cosaert Cédric Wolfs Stéphanie D. Lambert Geraldine J. Heynderickx Dirk Poelman Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders |
description |
Photocatalytic nanomaterials, using only light as the source of excitation, have been developed for the breakdown of volatile organic compounds (VOCs) in air for a long time. It is a tough challenge to immobilize these powder photocatalysts and prevent their entrainment with the gas stream. Conventional methods for making stable films typically require expensive deposition equipment and only allow the deposition of very thin layers with limited photocatalytic performance. The present work presents an alternative approach, using the combination of commercially available photocatalytic nanopowders and a polymer or inorganic sol–gel-based matrix. Analysis of the photocatalytic degradation of ethanol was studied for these layers on metallic substrates, proving a difference in photocatalytic activity for different types of stable layers. The sol–gel-based <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>TiO</mi><mn>2</mn></msub></semantics></math></inline-formula> layers showed an improved photocatalytic activity of the nanomaterials compared with the polymer <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>TiO</mi><mn>2</mn></msub></semantics></math></inline-formula> layers. In addition, the used preparation methods require only a limited amount of photocatalyst, little equipment, and allow easy upscaling. |
format |
article |
author |
Ewoud Cosaert Cédric Wolfs Stéphanie D. Lambert Geraldine J. Heynderickx Dirk Poelman |
author_facet |
Ewoud Cosaert Cédric Wolfs Stéphanie D. Lambert Geraldine J. Heynderickx Dirk Poelman |
author_sort |
Ewoud Cosaert |
title |
Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders |
title_short |
Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders |
title_full |
Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders |
title_fullStr |
Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders |
title_full_unstemmed |
Deposition of Hybrid Photocatalytic Layers for Air Purification Using Commercial TiO<sub>2</sub> Powders |
title_sort |
deposition of hybrid photocatalytic layers for air purification using commercial tio<sub>2</sub> powders |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/9d35bf0d190a43cf81aa105f4e7e1cf9 |
work_keys_str_mv |
AT ewoudcosaert depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders AT cedricwolfs depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders AT stephaniedlambert depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders AT geraldinejheynderickx depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders AT dirkpoelman depositionofhybridphotocatalyticlayersforairpurificationusingcommercialtiosub2subpowders |
_version_ |
1718431777432797184 |