Coulombic-enhanced hetero radical pairing interactions

Coulombic-enhanced hetero radical pairing interactions

Homo radical spin-pairing interactions between two identical aromatic radicals are common in supramolecular chemistry, but hetero interactions between two different aromatic radicals are seldom observed. Here, the authors find that hetero radical pairing between a radical cation and a radical anion,...

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Autores principales: Xujun Zheng, Yang Zhang, Ning Cao, Xin Li, Shuoqing Zhang, Renfeng Du, Haiying Wang, Zhenni Ye, Yan Wang, Fahe Cao, Haoran Li, Xin Hong, Andrew C.-H. Sue, Chuluo Yang, Wei-Guang Liu, Hao Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/9d4d859ee98548f3b23c16dda165e84a
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spelling oai:doaj.org-article:9d4d859ee98548f3b23c16dda165e84a2021-12-02T15:33:54ZCoulombic-enhanced hetero radical pairing interactions10.1038/s41467-018-04335-02041-1723https://doaj.org/article/9d4d859ee98548f3b23c16dda165e84a2018-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04335-0https://doaj.org/toc/2041-1723Homo radical spin-pairing interactions between two identical aromatic radicals are common in supramolecular chemistry, but hetero interactions between two different aromatic radicals are seldom observed. Here, the authors find that hetero radical pairing between a radical cation and a radical anion, together with Coulombic attraction, can drive host-guest recognition, representing a new supramolecular recognition motif.Xujun ZhengYang ZhangNing CaoXin LiShuoqing ZhangRenfeng DuHaiying WangZhenni YeYan WangFahe CaoHaoran LiXin HongAndrew C.-H. SueChuluo YangWei-Guang LiuHao LiNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Xujun Zheng
Yang Zhang
Ning Cao
Xin Li
Shuoqing Zhang
Renfeng Du
Haiying Wang
Zhenni Ye
Yan Wang
Fahe Cao
Haoran Li
Xin Hong
Andrew C.-H. Sue
Chuluo Yang
Wei-Guang Liu
Hao Li
Coulombic-enhanced hetero radical pairing interactions
description Homo radical spin-pairing interactions between two identical aromatic radicals are common in supramolecular chemistry, but hetero interactions between two different aromatic radicals are seldom observed. Here, the authors find that hetero radical pairing between a radical cation and a radical anion, together with Coulombic attraction, can drive host-guest recognition, representing a new supramolecular recognition motif.
format article
author Xujun Zheng
Yang Zhang
Ning Cao
Xin Li
Shuoqing Zhang
Renfeng Du
Haiying Wang
Zhenni Ye
Yan Wang
Fahe Cao
Haoran Li
Xin Hong
Andrew C.-H. Sue
Chuluo Yang
Wei-Guang Liu
Hao Li
author_facet Xujun Zheng
Yang Zhang
Ning Cao
Xin Li
Shuoqing Zhang
Renfeng Du
Haiying Wang
Zhenni Ye
Yan Wang
Fahe Cao
Haoran Li
Xin Hong
Andrew C.-H. Sue
Chuluo Yang
Wei-Guang Liu
Hao Li
author_sort Xujun Zheng
title Coulombic-enhanced hetero radical pairing interactions
title_short Coulombic-enhanced hetero radical pairing interactions
title_full Coulombic-enhanced hetero radical pairing interactions
title_fullStr Coulombic-enhanced hetero radical pairing interactions
title_full_unstemmed Coulombic-enhanced hetero radical pairing interactions
title_sort coulombic-enhanced hetero radical pairing interactions
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/9d4d859ee98548f3b23c16dda165e84a
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