β-Cyclodextrin-Calcium Complex Intercalated Hydrotalcites as Efficient Catalyst for Transesterification of Glycerol

β-cyclodextrin derivative intercalated MgAl-hydrotalcites (β-CD-Ca/LDH) was synthesized to convert glycerol into high value-added glycerol carbonate(GC) by transesterification of dimethyl carbonate (DMC) and glycerol in this paper. β-cyclodextrin-metal complexes and β-CD-Ca/LDH was characterized by...

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Autores principales:	Guanhao Liu, Jingyi Yang, Xinru Xu
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	β-CD-Ca hydrotalcites intercalation transesterification Chemical technology TP1-1185 Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/9d5b9d4fff0b4a9caa6cba446c432c9e
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spelling	oai:doaj.org-article:9d5b9d4fff0b4a9caa6cba446c432c9e2021-11-25T17:05:44Zβ-Cyclodextrin-Calcium Complex Intercalated Hydrotalcites as Efficient Catalyst for Transesterification of Glycerol10.3390/catal111113072073-4344https://doaj.org/article/9d5b9d4fff0b4a9caa6cba446c432c9e2021-10-01T00:00:00Zhttps://www.mdpi.com/2073-4344/11/11/1307https://doaj.org/toc/2073-4344β-cyclodextrin derivative intercalated MgAl-hydrotalcites (β-CD-Ca/LDH) was synthesized to convert glycerol into high value-added glycerol carbonate(GC) by transesterification of dimethyl carbonate (DMC) and glycerol in this paper. β-cyclodextrin-metal complexes and β-CD-Ca/LDH was characterized by XRD, FT-IR, SEM, XPS and nitrogen adsorption-desorption. The enrichment of organic reactants in the hydrophobic cavity of β-cyclodextrin improved the collision probability of reactants. The intercalation of β-cyclodextrin-calcium complex (β-CD-Ca) increased the pore size and basic strength of catalyst. The experiment results showed that the glycerol conversion was 93.7% and the GC yield was 91.8% catalyzed by β-CD-Ca/LDH when the molar ratio of DMC and glycerol was 3:1, the catalyst dosage was 4 wt.%, the reaction temperature was 75 °C and the reaction time was 100 min while the glycerol conversion was 49.4% and the GC yield was 48.6% catalyzed by MgAl-LDH under the same conditions.Guanhao LiuJingyi YangXinru XuMDPI AGarticleβ-CD-CahydrotalcitesintercalationtransesterificationChemical technologyTP1-1185ChemistryQD1-999ENCatalysts, Vol 11, Iss 1307, p 1307 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	β-CD-Ca hydrotalcites intercalation transesterification Chemical technology TP1-1185 Chemistry QD1-999
spellingShingle	β-CD-Ca hydrotalcites intercalation transesterification Chemical technology TP1-1185 Chemistry QD1-999 Guanhao Liu Jingyi Yang Xinru Xu β-Cyclodextrin-Calcium Complex Intercalated Hydrotalcites as Efficient Catalyst for Transesterification of Glycerol
description	β-cyclodextrin derivative intercalated MgAl-hydrotalcites (β-CD-Ca/LDH) was synthesized to convert glycerol into high value-added glycerol carbonate(GC) by transesterification of dimethyl carbonate (DMC) and glycerol in this paper. β-cyclodextrin-metal complexes and β-CD-Ca/LDH was characterized by XRD, FT-IR, SEM, XPS and nitrogen adsorption-desorption. The enrichment of organic reactants in the hydrophobic cavity of β-cyclodextrin improved the collision probability of reactants. The intercalation of β-cyclodextrin-calcium complex (β-CD-Ca) increased the pore size and basic strength of catalyst. The experiment results showed that the glycerol conversion was 93.7% and the GC yield was 91.8% catalyzed by β-CD-Ca/LDH when the molar ratio of DMC and glycerol was 3:1, the catalyst dosage was 4 wt.%, the reaction temperature was 75 °C and the reaction time was 100 min while the glycerol conversion was 49.4% and the GC yield was 48.6% catalyzed by MgAl-LDH under the same conditions.
format	article
author	Guanhao Liu Jingyi Yang Xinru Xu
author_facet	Guanhao Liu Jingyi Yang Xinru Xu
author_sort	Guanhao Liu
title	β-Cyclodextrin-Calcium Complex Intercalated Hydrotalcites as Efficient Catalyst for Transesterification of Glycerol
title_short	β-Cyclodextrin-Calcium Complex Intercalated Hydrotalcites as Efficient Catalyst for Transesterification of Glycerol
title_full	β-Cyclodextrin-Calcium Complex Intercalated Hydrotalcites as Efficient Catalyst for Transesterification of Glycerol
title_fullStr	β-Cyclodextrin-Calcium Complex Intercalated Hydrotalcites as Efficient Catalyst for Transesterification of Glycerol
title_full_unstemmed	β-Cyclodextrin-Calcium Complex Intercalated Hydrotalcites as Efficient Catalyst for Transesterification of Glycerol
title_sort	β-cyclodextrin-calcium complex intercalated hydrotalcites as efficient catalyst for transesterification of glycerol
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/9d5b9d4fff0b4a9caa6cba446c432c9e
work_keys_str_mv	AT guanhaoliu bcyclodextrincalciumcomplexintercalatedhydrotalcitesasefficientcatalystfortransesterificationofglycerol AT jingyiyang bcyclodextrincalciumcomplexintercalatedhydrotalcitesasefficientcatalystfortransesterificationofglycerol AT xinruxu bcyclodextrincalciumcomplexintercalatedhydrotalcitesasefficientcatalystfortransesterificationofglycerol
_version_	1718412728704434176

β-Cyclodextrin-Calcium Complex Intercalated Hydrotalcites as Efficient Catalyst for Transesterification of Glycerol

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