A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity
Lanthanide ions possess similar chemical properties, making their separation from one another challenging. Here the authors show that a tris-tridentate ligand causes high-precision metal ion self-sorting, leading to the selective assembly of tetrahedral M4L4 cages across the lanthanide series.
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Nature Portfolio
2018
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oai:doaj.org-article:9d86e352937445469eec0ba488696d542021-12-02T16:49:51ZA supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity10.1038/s41467-018-02940-72041-1723https://doaj.org/article/9d86e352937445469eec0ba488696d542018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-02940-7https://doaj.org/toc/2041-1723Lanthanide ions possess similar chemical properties, making their separation from one another challenging. Here the authors show that a tris-tridentate ligand causes high-precision metal ion self-sorting, leading to the selective assembly of tetrahedral M4L4 cages across the lanthanide series.Xiao-Zhen LiLi-Peng ZhouLiang-Liang YanYa-Min DongZhuan-Ling BaiXiao-Qi SunJuan DiwuShuao WangJean-Claude BünzliQing-Fu SunNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018) |
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DOAJ |
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DOAJ |
| language |
EN |
| topic |
Science Q |
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Science Q Xiao-Zhen Li Li-Peng Zhou Liang-Liang Yan Ya-Min Dong Zhuan-Ling Bai Xiao-Qi Sun Juan Diwu Shuao Wang Jean-Claude Bünzli Qing-Fu Sun A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity |
| description |
Lanthanide ions possess similar chemical properties, making their separation from one another challenging. Here the authors show that a tris-tridentate ligand causes high-precision metal ion self-sorting, leading to the selective assembly of tetrahedral M4L4 cages across the lanthanide series. |
| format |
article |
| author |
Xiao-Zhen Li Li-Peng Zhou Liang-Liang Yan Ya-Min Dong Zhuan-Ling Bai Xiao-Qi Sun Juan Diwu Shuao Wang Jean-Claude Bünzli Qing-Fu Sun |
| author_facet |
Xiao-Zhen Li Li-Peng Zhou Liang-Liang Yan Ya-Min Dong Zhuan-Ling Bai Xiao-Qi Sun Juan Diwu Shuao Wang Jean-Claude Bünzli Qing-Fu Sun |
| author_sort |
Xiao-Zhen Li |
| title |
A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity |
| title_short |
A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity |
| title_full |
A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity |
| title_fullStr |
A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity |
| title_full_unstemmed |
A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity |
| title_sort |
supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity |
| publisher |
Nature Portfolio |
| publishDate |
2018 |
| url |
https://doaj.org/article/9d86e352937445469eec0ba488696d54 |
| work_keys_str_mv |
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| _version_ |
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