A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity
Lanthanide ions possess similar chemical properties, making their separation from one another challenging. Here the authors show that a tris-tridentate ligand causes high-precision metal ion self-sorting, leading to the selective assembly of tetrahedral M4L4 cages across the lanthanide series.
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Autores principales: | Xiao-Zhen Li, Li-Peng Zhou, Liang-Liang Yan, Ya-Min Dong, Zhuan-Ling Bai, Xiao-Qi Sun, Juan Diwu, Shuao Wang, Jean-Claude Bünzli, Qing-Fu Sun |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2018
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Materias: | |
Acceso en línea: | https://doaj.org/article/9d86e352937445469eec0ba488696d54 |
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