Synthesis of AgN5 and its extended 3D energetic framework

The pentazolate anion shows great promise for high energy density materials, but has only been isolated alongside non-energetic counter ions that impede its energetic properties. Here, the authors synthesize a silver cyclo-N5-complex devoid of stabilizing ions, as well as a complementary [Ag(NH3)2]+...

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Autores principales: Chengguo Sun, Chong Zhang, Chao Jiang, Chen Yang, Yang Du, Yue Zhao, Bingcheng Hu, Zhansheng Zheng, Karl O. Christe
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/9dd0ca13867248b5be31f98e46acbd22
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Sumario:The pentazolate anion shows great promise for high energy density materials, but has only been isolated alongside non-energetic counter ions that impede its energetic properties. Here, the authors synthesize a silver cyclo-N5-complex devoid of stabilizing ions, as well as a complementary [Ag(NH3)2]+[Ag3(N5)4]− 3D framework.